Substituted 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-diones, their preparation and their use

ABSTRACT

The present invention relates to 1-H-3-phenyl-5-cyloalkylpyrrolidine-2,4-diones of the formula (I) ##STR1## in which A represents optionally substituted cycloalkyl and 
     B represents hydrogen or optionally substituted alkyl, 
     X represents alkyl, halogen or alkoxy, 
     Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl, 
     Z represents alkyl, halogen or alkoxy, 
     n represents a number 0, 1, 2 or 3, 
     G represents hydrogen (a) or the groups ##STR2##  These compounds possess herbicidal and pesticidal activity.

The invention relates to new 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-diones, to a plurality of processes for their preparation and to their use as pesticides (in particular as insecticides and acaricides) and as herbicides.

3-Aryl-pyrrolidine-2,4-diones have previously been described as having pharmaceutical properties (S. Suzuki et al. Chem. Pharm. Bull. 15 1120 (1967)). Furthermore, N-phenyl-pyrrolidine-2,4-diones were synthesized by R. Schmierer and H. Mildenberger (Liebigs Ann. Chem. 1985 1095). A biological activity of these compounds has not been described.

EP-A 0,262,399 discloses compounds of a similar structure (3-aryl-pyrrolidine-2,4-diones), from which, however, no herbicidal, insecticidal or acaricidal activity has been disclosed. Unsubstituted, bicyclic 3-aryl-pyrrolidine-2,4-dione derivatives (EP-A 355,599) and (EP 415,211), substituted bicyclic 3-aryl-pyrrolidine-2,4-dione derivatives (EP 501,129) and substituted monocyclic 3-aryl-pyrrolidine-2,4-dione derivatives (EP-A 377,893), (EP 442,077) and (EP 497,127) are known and have a herbicidal, insecticidal or acaricidal activity.

Also known are polycyclic 3-arylpyrrolidine-2,4-dione derivatives (EP 442,073) and 1-H-3-arylpyrrolidine-dione derivatives (EP 456,063) and (EP 521,334).

New 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-diones of the formula (I) ##STR3## have now been found, in which

A represents optionally substituted cycloalkyl and

B represents hydrogen or optionally substituted alkyl,

X represents alkyl, halogen or alkoxy,

Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl,

Z represents alkyl, halogen or alkoxy,

n represents a number 0, 1, 2 or 3,

G represents hydrogen (a) or the groups ##STR4## E represents a metal ion equivalent or an ammonium ion, L and M represent oxygen and/or sulphur,

R¹ represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl, it being possible for the latter to be interrupted by hetero atoms, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl,

R² represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or in each case optionally substituted cycloalkyl, phenyl or benzyl,

R³, R⁴ and R⁵ independently of one another represent in each case optionally halogen-substituted alkyl, alkoxy, cycloalkyloxy, alkylamino, dialkylamino, alkylthio, alkenylthio or cycloalkylthio and in each case optionally substituted phenyl, phenoxy, benzyloxy or phenylthio,

R⁶ and R⁷ independently of one another represent hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxy or alkoxyalkyl, optionally substituted phenyl, optionally substituted benzyl, or together with the N-atom to which they are bound represent a cycle which is optionally interrupted by oxygen or sulphur.

Taking into consideration the various meanings (a), (b), (c), (d), (e), (f) and (g) of group G in the general formula (I), the following main structures (Ia) to (Ig) result: ##STR5## in which A, B, E, L, M, X, Y, Z_(n), R¹, R², R³, R⁴, R⁵, R⁶ and R⁷ have the abovementioned meanings.

Due to one or more centres of chirality, the compounds of the formula (Ia)-(Ig) are generally obtained as a mixture of stereoisomers which, if appropriate, can be separated in the customary manner. They can be used in the form of their diastereomer mixtures and also as pure diastereomers or enantiomers. The following text will always mention compounds of the formula (Ia) to (Ig), for simplicity's sake, even though this is to be understood as meaning the pure compounds and also the mixtures containing various proportions of isomeric, enantiomeric and stereomeric compounds.

Furthermore, it has been found that the new substituted 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-diones of the formula (I) are obtained by one of the processes described below.

(A) 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-diones or their enols of the formula (Ia) ##STR6## in which A, B, X, Y, Z and n have the abovementioned meaning, are obtained when

N-acylamino acid esters of the formula (II) ##STR7## in which A, B, X, Y, Z and n have the abovementioned meaning and

R⁸ represents alkyl,

are subjected to an intramolecular condensation reaction in the presence of a diluent and in the presence of a base;

or

(B) compounds of the formula (Ib) ##STR8## in which A, B, X, Y, Z, R¹ and n have the abovementioned meaning

are obtained when compounds of the formula (Ia) ##STR9## in which A, B, X, Y, Z and n have the abovementioned meaning, are reacted

α) with acid halides of the general formula (III) ##STR10## in which R¹ has the abovementioned meaning and

Hal represents halogen, in particular chlorine and bromine,

if appropriate in the presence of a diluent and if appropriate in the presence of an acid-binding agent,

or

β) with carboxylic anhydrides of the general formula (IV)

    R.sup.1 --CO--O--CO--R.sup.1                               (IV)

in which

R¹ has the abovementioned meaning,

if appropriate in the presence of a diluent and if appropriate in the presence of an acid-binding agent;

or

(C) compounds of the formula (Ic-1) ##STR11## in which A, B, X, Y, Z, R² and n have the abovementioned meaning and

M represents oxygen or sulphur,

are obtained when compounds of the formula (Ia) ##STR12## in which A, B, X, Y, Z and n have the abovementioned meaning, are reacted with chloroformic ester or chloroformic thioester of the general formula (V)

    R.sup.2 --M--CO--Cl                                        (V)

in which

R² and M have the abovementioned meaning,

if appropriate in the presence of a diluent and if appropriate in the presence of an acid-binding agent;

or

(D) compounds of the formula (Ic-2) ##STR13## in which A, B, R², X, Y, Z and n have the abovementioned meaning and

M represents oxygen or sulphur,

are obtained when compounds of the formula (Ia) ##STR14## in which A, B, X, Y, Z and n have the abovementioned meaning, are reacted

α) with chloromonothioformic esters or chlorodithioformic esters of the general formula (VI) ##STR15## in which M and R² have the abovementioned meaning,

if appropriate in the presence of a diluent and if appropriate in the presence of an acid-binding agent,

or

β) with carbon disulphide and subsequently with alkyl halides of the general formula (VII)

    R.sup.2 --Hal                                              (VII)

in which

R² has the abovementioned meaning and

Hal represents chlorine, bromine or iodine,

if appropriate in the presence of a diluent; or

(E) compounds of the formula (Id) ##STR16## in which A, B, X, Y, Z, R³ and n have the abovementioned meaning,

are obtained when compounds of the formula (Ia) ##STR17## in which A, B, X, Y, Z and n have the abovementioned meaning,

are reacted with sulphonyl chlorides of the general formula (VIII)

    R.sup.3 --SO.sub.2 --Cl                                    (VIII)

in which

R³ has the abovementioned meaning,

if appropriate in the presence of a diluent and if appropriate in the presence of an acid-binding agent;

or

(F) compounds of the formula (Ie) ##STR18## in which A, B, L, X, Y, Z, R⁴, R⁵ and n have the abovementioned meaning,

are obtained when

1-H-3-aryl-pyrrolidine-2,4-diones of the formula (Ia) or their enols ##STR19## in which A, B, X, Y, Z and n have the abovementioned meaning,

are reacted with phosphorus compounds of the general formula (IX) ##STR20## in which L, R⁴ and R⁵ have the abovementioned meaning and

Hal represents halogen, in particular chlorine or bromine,

if appropriate in the presence of a diluent and if appropriate in the presence of an acid-binding agent;

or

(G) compounds of the formula (If) ##STR21## in which A, B, X, Y, Z and n have the abovementioned meaning, and

E represents a metal ion equivalent or an ammonium ion,

are obtained when compounds of the formula (Ia) ##STR22## in which A, B, X, Y, Z and n have the abovementioned meaning,

are reacted with metal hydroxides or amines of the general formulae (X) and (XI) ##STR23## in which Me represents mono- or divalent metal ions,

t represents the number 1 or 2 and

R¹⁰, R¹¹ and R¹² independently of one another represent hydrogen and alkyl,

if appropriate in the presence of a diluent.

(H) Furthermore, it has been found that compounds of the formula (I) ##STR24## in which A, B, L, X, Y, Z, R⁶, R⁷ and n have the abovementioned meaning,

are obtained when compounds of the formula (Ia) ##STR25## in which A, B, X, Y, Z and n have the abovementioned meaning, are reacted

α) with compounds of the general formula (XII)

    R.sup.6 --N═C═L                                    (XII)

in which

L and R⁶ have the abovementioned meaning,

if appropriate in the presence of a diluent and if appropriate in the presence of a catalyst

or

β) with carbamoyl chlorides or thiocarbamoyl chlorides of the general formula (XIII) ##STR26## in which L, R⁶ and R⁷ have the abovementioned meaning,

if appropriate in the presence of a diluent and if appropriate in the presence of an acid-binding agent.

Furthermore, it has been found that the new 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-diones of the formula (I) are distinguished by outstanding insecticidal, acaricidal and herbicidal activities.

The following applies to the general formulae of the present application:

A preferably represents C₃ -C₁₀ -cycloalkyl which is optionally substituted by halogen, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₁ -C₄ -halogenoalkyl or C₁ -C₄ -halogenoalkoxy,

B preferably represents hydrogen or optionally halogen-substituted straight-chain or branched alkyl,

A particularly preferably represents C₃ -C₈ -cycloalkyl which is optionally substituted by fluorine, chlorine, C₁ -C₅ -alkyl, C₁ -C₅ -alkoxy, C₁ -C₂ -halogenoalkyl or C₁ -C₂ -halogenoalkoxy,

B particularly preferably represents hydrogen or straight-chain or branched C₁ -C₆ -alkyl which is optionally substituted by chlorine or fluorine.

A very particularly preferably represents C₃ -C₆ -cycloalkyl which is optionally substituted by fluorine, methyl, ethyl, propyl, i-propyl, butyl, i-butyl, s-butyl, t-butyl, methoxy, ethoxy, propoxy, i-propoxy, trifluoromethyl or trifluoromethoxy,

B very particularly preferably represents hydrogen or methyl, ethyl, propyl, i-propyl, butyl, i-butyl, s-butyl or t-butyl, each of which is optionally substituted by fluorine.

X preferably represents C₁ -C₆ -alkyl, halogen or C₁ -C₆ -alkoxy.

X particularly preferably represents C₁ -C₄ -alkyl, halogen or C₁ -C₄ -alkoxy.

X very particularly preferably represents methyl, ethyl, propyl, i-propyl, fluorine, chlorine, bromine, methoxy or ethoxy.

Y preferably represents hydrogen, C₁ -C₆ -alkyl, halogen, C₁ -C₆ -alkoxy or C₁ -C₃ -halogenoalkyl.

Y particularly preferably represents hydrogen, C₁ -C₄ -alkyl, halogen, C₁ -C₄ -alkoxy or C₁ -C₂ -halogenoalkyl.

Y very particularly preferably represents hydrogen, methyl, ethyl, propyl, i-propyl, butyl, i-butyl, tert.-butyl, fluorine, chlorine, bromine, methoxy, ethoxy or trifluoromethyl.

Z preferably represents C₁ -C₆ -alkyl, halogen or C₁ -C₆ -alkoxy.

Z particularly preferably represents C₁ -C₄ -alkyl, halogen or C₁ -C₄ -alkoxy.

Z very particularly preferably represents methyl, ethyl, propyl, i-propyl, butyl, i-butyl, tert.-butyl, fluorine, chlorine, bromine, methoxy or ethoxy.

G preferably represents hydrogen (a) or the groups ##STR27## in which E in each case represents a metal ion equivalent or an ammonium ion and

L and M in each case represent oxygen and/or sulphur,

R¹ represents in each case optionally halogen-substituted C₁ -C₂₀ -alkyl, C₂ -C₂₀ -alkenyl, C₁ -C₈ -alkoxy-C₁ -C₈ -alkyl, C₁ -C₈ -alkylthio-C₁ -C₈ -alkyl, C₁ -C₈ -polyalkoxy-C₂ -C₈ -alkyl or cycloalkyl having 3 to 8 ring atoms, it being possible for the latter to be interrupted by oxygen and/or sulphur atoms,

or represents phenyl which is optionally substituted by halogen, nitro, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₁ -C₆ -halogenoalkyl, C₁ -C₆ -halogenoalkoxy, C₁ -C₆ -alkylthio or -C₁ -C₆ -alkylsulphonyl,

or represents phenyl-C₁ -C₆ -alkyl which is optionally substituted by halogen, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₁ -C₆ -halogenoalkyl or C₁ -C₆ -halogenoalkoxy,

or represents hetaryl which is optionally substituted by halogen and/or C₁ -C₆ -alkyl,

or represents phenoxy-C₁ -C₆ -alkyl which is optionally substituted by halogen and/or C₁ -C₆ -alkyl,

or represents hetaryloxy-C₁ -C₆ -alkyl which is optionally substituted by halogen, amino and/or C₁ -C₆ -alkyl,

R² represents in each case optionally halogen-substituted C₁ -C₂₀ -alkyl, C₃ -C₂₀ -alkenyl, C₁ -C₈ -alkoxy-C₂ -C₈ -alkyl or C₁ -C₈ -polyalkoxy-C₂ -C₈ -alkyl,

or represents C₃ -C₈ -cycloalkyl which is optionally substituted by halogen, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy and/or C₁ -C₆ -alkylthio,

or represents phenyl or benzyl, each of which is optionally substituted by halogen, nitro, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy or C₁ -C₆ -halogenoalkyl,

R³, R⁴ and R⁵ independently of one another represent in each case optionally halogen-substituted C₁ -C₈ -alkyl, C₁ -C₈ -alkoxy, C₃ -C₇ -cycloalkyloxy, C₁ -C₈ -alkylamino, Di-(C₁ -C₈)-alkylamino C₁ -C₈ -alkylthio, C₃ -C₈ -alkenylthio or C₃ -C₇ -cycloalkylthio, or represent phenyl, phenoxy, benzyloxy or phenylthio, each of which is optionally substituted by halogen, nitro, cyano, C₁ -C₄ -alkoxy, C₁ -C₄ -halogenoalkoxy, C₁ -C₄ -alkylthio, C₁ -C₄ -halogenoalkylthio, C₁ -C₄ -alkyl or C₁ -C₄ -halogenoalkyl,

R⁶ and R⁷ independently of one another represent hydrogen or represent in each case optionally halogen-substituted C₁ -C₈ -alkyl, C₃ -C₈ -cycloalkyl, C₁ -C₈ -alkoxy, C₃ -C₈ -alkenyl or C₁ -C₈ -alkoxy-C₂ -C₈ -alkyl, or represent phenyl which is optionally substituted by halogen, C₁ -C₈ -halogenoalkyl, C₁ -C₈ -alkyl or C₁ -C₈ -alkoxy, or represent benzyl which is optionally substituted by halogen, C₁ -C₈ -alkyl, C₁ -C₈ -halogenoalkyl or C₁ -C₈ -alkoxy, or together with the N-atom to which they are bound represent a ring having 3-6 atoms which is optionally interrupted by oxygen or sulphur,

G particularly preferably represents hydrogen (a) or the groups ##STR28## in which E represents a metal ion equivalent or an ammonium ion,

L and M in each case represent oxygen and/or sulphur,

R¹ represents in each case optionally halogen-substituted C₁ -C₁₆ -alkyl, C₂ -C₁₆ -alkenyl, C₁ -C₆ -alkoxy-C₁ -C₆ -alkyl, C₁ -C₁₆ -alkylthio-C₁ -C₆ -alkyl, C₁ -C₆ -polyalkoxy-C₂ -C₆ -alkyl or cycloalkyl having 3 to 7 ring atoms which can be interrupted by 1-2 oxygen and/or sulphur atoms,

or represents phenyl which is optionally substituted by halogen, nitro, C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy, C₁ -C₃ -halogenoalkyl, C₁ -C₃ -halogenoalkoxy C₁ -C₆ -alkylthio or C₁ -C₆ -alkylsulphonyl,

or represents phenyl-C₁ -C₄ -alkyl which is optionally substituted by halogen, C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy, C₁ -C₃ -halogenoalkyl or C₁ -C₃ -halogenoalkoxy,

or represents hetaryl which is optionally substituted by fluorine, chlorine, bromine and/or C₁ -C₄ -alkyl,

or represents phenoxy-C₁ -C₅ -alkyl which is optionally substituted by fluorine, chlorine, bromine and/or C₁ -C₄ -alkyl,

or represents hetaryloxy-C₁ -C₅ -alkyl which is optionally substituted by fluorine, chlorine, bromine, amino and/or C₁ -C₄ -alkyl,

R² represents in each case optionally halogen-substituted C₁ -C₁₆ -alkyl, C₃ -C₁₆ -alkenyl, C₁ -C₆ -alkoxy-C₂ -C₆ -alkyl or C₁ -C₆ -polyalkoxy-C₂ -C₆ -alkyl,

or represents C₃ -C₇ -cycloalkyl which is optionally substituted by halogen, C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy and/or C₁ -C₄ -alkylthio,

or represents phenyl or benzyl, each of which is optionally substituted by halogen, nitro, C₁ -C₄ -alkyl, C₁ -C₃ -alkoxy or C₁ -C₃ -halogenoalkyl,

R³, R⁴ and R⁵ independently of one another represent in each case optionally halogen-substituted C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₃ -C₆ -cycloalkyloxy, C₁ -C₆ -alkylamino, di-(C₁ -C₆ -alkylamino, C₁ -C₆ -alkylthio, C₃ -C₆ -alkenylthio or C₃ -C₆ -cycloalkylthio, or represent phenyl, phenoxy, benzyloxy, or phenylthio, each of which is optionally substituted by fluorine, chlorine, bromine, nitro, cyano, C₁ -C₃ -alkoxy, C₁ -C₃ -halogenoalkoxy, C₁ -C₃ -alkylthio, C₁ -C₃ -halogenoalkylthio, C₁ -C₃ -alkyl or C₁ -C₃ -halogenoalkyl,

R⁶ and R⁷ independently of one another represent hydrogen, or represent in each case optionally halogen-substituted C₁ -C₆ -alkyl, C₃ -C₆ -cycloalkyl, C₁ -C₆ -alkoxy, C₃ -C₆ -alkenyl or C₁ -C₆ -alkoxy-C₂ -C₆ -alkyl, or represent phenyl which is optionally substituted by halogen, C₁ -C₅ -halogenoalkyl, C₁ -C₅ -alkyl or C₁ -C₅ -alkoxy, or represent benzyl which is optionally substituted by halogen, C₁ -C₅ -alkyl, C₁ -C₅ -halogenoalkyl or C₁ -C₅ -alkoxy, or together with the N-atom to which they are bound represent a ring having 3-6 C-atoms which is Optionally substituted by oxygen or sulphur,

G very particularly preferably represents hydrogen (a) or the groups ##STR29## in which E represents a metal ion equivalent or an ammonium ion

and

L and M represent oxygen and/or sulphur,

R¹ represents in each case optionally fluorine- or chlorine-substituted C₁ -C₁₄ -alkyl, C₂ -C₁₄ -alkenyl, C₁ -C₄ -alkoxy-C₁ -C₆ -alkyl, C₁ -C₄ -alkylthio-C₁ -C₆ -alkyl, C₁ -C₄ -polyalkoxy-C₂ -C₄ -alkyl or cycloalkyl having 3 to 6 ring atoms which can be interrupted by 1 to 2 oxygen and/or sulphur atoms,

or represents phenyl which is optionally substituted by fluorine, chlorine, bromine, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy, trifluoromethyl, trifluoromethoxy, nitro, methylthio, ethylthio, methylsulphonyl or ethylsulphonyl,

or represents phenyl-C₁ -C₃ -alkyl which is optionally substituted by fluorine, chlorine, bromine, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy,

or represents furanoyl, thienyl, pyridyl, pyrimidyl, thiazolyl and pyrazolyl, each of which is optionally substituted by fluorine, chlorine, bromine, methyl or ethyl,

or represents phenoxy-C₁ -C₄ -alkyl which is optionally substituted by fluorine, chlorine, methyl or ethyl,

or represents pyridyloxy-C₁ -C₄ -alkyl, pyrimidyloxy-C₁ -C₄ -alkyl and thiazolyloxy-C₁ -C₄ -alkyl, each of which is optionally substituted by fluorine, chlorine, amino, methyl or ethyl,

represents C₁ -C₁₄ -alkyl, C₃ -C₁₄ -alkenyl, C₁ -C₄ -alkoxy-C₂ -C₆ -alkyl or C₁ -C₄ -polyalkoxy-C₂ -C₆ -alkyl, each of which is optionally substituted by fluorine or chlorine,

or represents C₃ -C₆ -cycloalkyl which is optionally substituted by fluorine, chlorine, methyl, ethyl, propyl, methoxy, ethoxy, methylthio or ethylthio,

or represents phenyl or benzyl, each of which is optionally substituted by fluorine, chlorine, nitro, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy or trifluoromethyl,

R³, R⁴ and R⁵ independently of one another represent C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy, C₁ -C₄ -alkylamino, di-(C₁ -C₄)-alkylamino or C₁ -C₄ -alkylthio, each of which is optionally substituted by fluorine or chlorine, or represent phenyl, phenoxy, benzyloxy or phenylthio, each of which is optionally substituted by fluorine, chlorine, bromine, nitro, cyano, C₁ -C₂ -alkoxy, C₁ -C₄ -fluoroalkoxy, C₁ -C₂ -alkylthio, C₁ -C₂ -fluoroalkylthio or C₁ -C₃ -alkyl.

R⁶ and R⁷ independently of one another represent hydrogen, or represent C₁ -C₄ -alkyl, C₃ -C₆ -cycloalkyl, C₁ -C₄ -alkoxy, C₃ -C₄ -alkenyl or C₁ -C₄ -alkoxy-C₂ -C₄ -alkyl, each of which is optionally substituted by fluorine, chlorine or bromine, or represent phenyl which is optionally substituted by fluorine, chlorine, bromine, C₁ -C₄ -halogenoalkyl, C₁ -C₄ -alkyl or C₁ -C₄ -alkoxy, or represent benzyl which is optionally substituted by fluorine, chlorine, bromine, C₁ -C₄ -alkyl, C₁ -C₄ -halogenoalkyl or C₁ -C₄ -alkoxy, or together with the N-atom to which they are bound represent a ring having 4-6 C-atoms which is optionally substituted by oxygen or sulphur.

The following compounds of the formula (Ia) may be mentioned individually in addition to the compounds mentioned in the Preparation Examples:

                  TABLE 1                                                          ______________________________________                                          ##STR30##                    (Ia)                                             X         Y         Z.sub.n   A*      B                                        ______________________________________                                         Cl        Cl        H         C.sub.3 H.sub.5                                                                        CH.sub.3                                 Cl        H         6-Cl      C.sub.3 H.sub.5                                                                        CH.sub.3                                 Cl        H         6-F       C.sub.3 H.sub.5                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3  H         C.sub.3 H.sub.5                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3  6-CH.sub.3                                                                               C.sub.3 H.sub.5                                                                        CH.sub.3                                 Cl        Cl        H         C.sub.5 H.sub.9                                                                        CH.sub.3                                 Cl        H         6-Cl      C.sub.5 H.sub.9                                                                        CH.sub.3                                 Cl        H         6-F       C.sub.5 H.sub.9                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3  H         C.sub.5 H.sub.9                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3  6-CH.sub.3                                                                               C.sub.5 H.sub.9                                                                        CH.sub.3                                 Cl        Cl        H         C.sub.6 H.sub.11                                                                       CH.sub.3                                 Cl        H         6-Cl      C.sub.6 H.sub.11                                                                       CH.sub.3                                 Cl        H         6-F       C.sub.6 H.sub.11                                                                       CH.sub.3                                 CH.sub.3  CH.sub.3  H         C.sub.6 H.sub.11                                                                       CH.sub.3                                 CH.sub.3  CH.sub.3  6-CH.sub.3                                                                               C.sub.6 H.sub.11                                                                       CH.sub.3                                 ______________________________________                                          ##STR31##                                                                     -  The following compounds of the formula (Ib) may be mentioned                 individually in addition to the compounds mentioned in the Preparation      Examples:

                  TABLE 2                                                          ______________________________________                                          ##STR32##                    (Ib)                                             A*    B      X      Y    Z.sub.n                                                                              R.sup.1                                         ______________________________________                                         C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     CH.sub.3                                        C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     C.sub.2 H.sub.5                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     C.sub.3 H.sub.7                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     i-C.sub.3 H.sub.7                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     C.sub.4 H.sub.9                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     i-C.sub.4 H.sub.9                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     t-C.sub.4 H.sub.9                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     t-C.sub.4 H.sub.9CH.sub.2                       C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR33##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     H.sub.3 CSCH.sub.2                              C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H     (CH.sub.3).sub.2 CCH                            C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR34##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR35##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR36##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR37##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR38##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR39##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     CH.sub.3                                        C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.2 H.sub.5                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.3 H.sub.7                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.3 H.sub.7                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.4 H.sub.9                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.4 H.sub.9                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     t-C.sub.4 H.sub.9                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     t-C.sub.4 H.sub.9CH.sub.2                       C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR40##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.3 CSCH.sub.2                              C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     (CH.sub.3).sub.2 CCH                            C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR41##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR42##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR43##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR44##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR45##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR46##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           CH.sub.3                                        C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.2 H.sub.5                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.3 H.sub.7                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.3 H.sub.7                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.4 H.sub.9                                 C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.4 H.sub.9                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           t-C.sub.4 H.sub.9                               C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           t-C.sub.4 H.sub.9CH.sub.2                       C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR47##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.3 CSCH.sub.2                              C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           (CH.sub.3).sub.2 CCH                            C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR48##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR49##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR50##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR51##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR52##                                      C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR53##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     CH.sub.3                                        C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     C.sub.2 H.sub.5                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     C.sub.3 H.sub.7                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     i-C.sub.3 H.sub.7                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     C.sub.4 H.sub.9                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     i-C.sub.4 H.sub.9                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     t-C.sub.4 H.sub.9                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     t-C.sub.4 H.sub.9CH.sub.2                       C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR54##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     H.sub.3 CSCH.sub.2                              C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H     (CH.sub.3).sub.2 CCH                            C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR55##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR56##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR57##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR58##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR59##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR60##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     CH.sub.3                                        C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.2 H.sub.5                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.3 H.sub.7                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.3 H.sub.7                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.4 H.sub.9                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.4 H.sub.9                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     t-C.sub.4 H.sub.9                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     t-C.sub.4 H.sub.9CH.sub.2                       C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR61##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.3 CSCH.sub.2                              C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     (CH.sub.3).sub.2 CCH                            C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR62##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR63##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR64##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR65##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR66##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR67##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           CH.sub.3                                        C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.2 H.sub.5                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.3 H.sub.7                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.3 H.sub.7                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.4 H.sub.9                                 C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.4 H.sub.9                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           t-C.sub.4 H.sub.9                               C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           t-C.sub.4 H.sub.9CH.sub.2                       C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR68##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.3 CSCH.sub.2                              C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           (CH.sub.3).sub.2 CCH                            C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR69##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR70##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR71##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR72##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR73##                                      C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR74##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     CH.sub.3                                        C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     C.sub.2 H.sub.5                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     C.sub.3 H.sub.7                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     i-C.sub.3 H.sub.7                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     C.sub.4 H.sub.9                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     i-C.sub.4 H.sub.9                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     t-C.sub.4 H.sub.9                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     t-C.sub.4 H.sub.9CH.sub.2                       C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR75##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     H.sub.3 CSCH.sub.2                              C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H     (CH.sub.3).sub.2 CCH                            C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR76##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR77##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR78##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR79##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR80##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              Cl     Cl   H                                                                                     ##STR81##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     CH.sub.3                                        C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.2 H.sub.5                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.3 H.sub.7                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.3 H.sub.7                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     C.sub.4 H.sub.9                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.4 H.sub.9                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     t-C.sub.4 H.sub.9                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     ClCH.sub.2C(CH.sub.3).sub.2                     C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     t-C.sub.4 H.sub.9CH.sub.2                       C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR82##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     H.sub.3 CSCH.sub.2                              C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H     (CH.sub.3).sub.2 CCH                            C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR83##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR84##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR85##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR86##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR87##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            H                                                                                     ##STR88##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           CH.sub.3                                        C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.2 H.sub.5                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.3 H.sub.7                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.3 H.sub.7                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           C.sub.4 H.sub.9                                 C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.4 H.sub.9                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           t-C.sub.4 H.sub.9                               C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.5 C.sub.2C(CH.sub.3).sub.2                C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           i-C.sub.3 H.sub.7C(CH.sub.3).sub.2              C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           Cl-CH.sub.2C(CH.sub.3).sub.2                    C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.3 COCH.sub.2C(CH.sub.3).sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           t-C.sub.4 H.sub.9CH.sub.2                       C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR89##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           H.sub.3 CSCH.sub.2                              C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           (CH.sub.3).sub.2 CCH                            C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR90##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR91##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR92##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR93##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR94##                                      C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                            ##STR95##                                      ______________________________________                                          A* =-                                                                          ##STR96##                                                                     -  The following compounds of the formula (Ic) may be mentioned                 individually in addition to the compounds mentioned in the preparation      Examples:

                  TABLE 3                                                          ______________________________________                                          ##STR97##                    (Ic)                                             A*    B        X      Y    Z.sub.n                                                                              L   M   R.sup.2                               ______________________________________                                         C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O   CH.sub.3                              C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O   C.sub.2 H.sub.5                       C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O   C.sub.3 H.sub.7                       C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O   i-C.sub.3 H.sub.7                     C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O   i-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O   s-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O   t-C.sub.4 H.sub.9                     C.sub.3 H.sub.7                                                                      CH.sub.3 Cl     Cl   H     O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR98##                            C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR99##                            C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR100##                           C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   CH.sub.3                              C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   C.sub.2 H.sub.5                       C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   C.sub.3 H.sub.7                       C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   i-C.sub.3 H.sub.7                     C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   i-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   s-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   t-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 Cl     Cl   H     O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   CH.sub.3                              C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   C.sub.2 H.sub.5                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   C.sub.3 H.sub.7                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   i-C.sub.3 H.sub.7                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   i-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   s-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   t-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR101##                           C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR102##                           C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR103##                           C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   CH.sub.3                              C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   C.sub.2 H.sub.5                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   C.sub.3 H.sub.7                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   i-C.sub.3 H.sub.7                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   i-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   s-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   t-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   CH.sub.3                              C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   C.sub.2 H.sub.5                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   C.sub.3 H.sub.7                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   i-C.sub.3 H.sub.7                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   i-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   s-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   t-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR104##                           C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR105##                           C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR106##                           C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   CH.sub.3                              C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   C.sub.2 H.sub.5                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   C.sub.3 H.sub.7                       C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   i-C.sub.3 H.sub.7                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   i-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   s-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   t-C.sub.4 H.sub.9                     C.sub.3 H.sub.5                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O   CH.sub.3                              C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O   C.sub.2 H.sub.5                       C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O   C.sub.3 H.sub.7                       C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O   i-C.sub.3 H.sub.7                     C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O   i-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O   s-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CC.sub.5 H.sub.9                                                                        Cl     Cl   H     O   O   t-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR107##                           C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR108##                           C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR109##                           C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   CH.sub.3                              C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   C.sub.2 H.sub.5                       C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   C.sub.3 H.sub.7                       C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   i-C.sub.3 H.sub.7                     C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   i-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   s-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   t-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 Cl     Cl   H     O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   CH.sub.3                              C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   C.sub.2 H.sub.5                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   C.sub.3 H.sub.7                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   i-C.sub.3 H.sub.7                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   i-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   s-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   t-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR110##                           C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR111##                           C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR112##                           C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   CH.sub.3                              C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   C.sub.2 H.sub.5                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   C.sub.3 H.sub.7                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   i-C.sub.3 H.sub.7                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   i-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   s-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   t-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   CH.sub.3                              C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   C.sub.2 H.sub.5                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   C.sub.3 H.sub.7                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   i-C.sub.3 H.sub.7                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   i-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   s-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   t-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR113##                           C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR114##                           C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR115##                           C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   CH.sub.3                              C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   C.sub.2 H.sub.5                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   C.sub.3 H.sub.7                       C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   i-C.sub.3 H.sub.7                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   i-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   s-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   t-C.sub.4 H.sub.9                     C.sub.5 H.sub.9                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   CH.sub.3                              C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   C.sub.2 H.sub.5                       C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   C.sub.3 H.sub.7                       C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   i-C.sub.3 H.sub.7                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   i-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   s-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   t-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR116##                           C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR117##                           C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   O                                                                                   ##STR118##                           C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   CH.sub.3                              C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   C.sub.2 H.sub.5                       C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   C.sub.3 H.sub.7                       C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   i-C.sub.3 H.sub.7                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   i-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   s-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   t-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 Cl     Cl   H     O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   CH.sub.3                              C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   C.sub.2 H.sub.5                       C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   C.sub.3 H.sub.7                       C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   i-C.sub.3 H.sub.7                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   i-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   s-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   t-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR119##                           C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR120##                           C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   O                                                                                   ##STR121##                           C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   CH.sub.3                              C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   C.sub.2 H.sub.5                       .sub.6 H.sub.11                                                                      CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   C.sub.3 H.sub.7                       C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   i-C.sub.3 H.sub.7                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   i-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   s-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   t-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            H     O   S   t-C.sub.4 H.sub.9CH.sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   CH.sub.3                              C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   C.sub.2 H.sub.5                       C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   C.sub.3 H.sub.7                       C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   i-C.sub.3 H.sub.7                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   i-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   s-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   t-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O   t-C.sub.4 H.sub.9CH.sub.2             C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR122##                           C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR123##                           C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   O                                                                                   ##STR124##                           C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   CH.sub.3                              C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   C.sub.2 H.sub.5                       C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   C.sub.3 H.sub.7                       C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   i-C.sub.3 H.sub.7                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   i-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   s-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   t-C.sub.4 H.sub.9                     C.sub.6 H.sub.11                                                                     CH.sub.3 CH.sub.3                                                                              CH.sub.3                                                                            6-CH.sub.3                                                                           O   S   t-C.sub.4 H.sub.9CH.sub.2             ______________________________________                                          A* =-                                                                          ##STR125##                                                                    -  The following compounds of the formula (Id) may be mentioned                 individually in addition to the compounds mentioned in the Preparation      Examples:

                  TABLE 4                                                          ______________________________________                                          ##STR126##                   (Id)                                             X         Y        Z.sub.n    A*      B                                        ______________________________________                                         Cl        Cl       H          C.sub.3 H.sub.5                                                                        CH.sub.3                                 Cl        H        6-Cl       C.sub.3 H.sub.5                                                                        CH.sub.3                                 Cl        H        6-F        C.sub.3 H.sub.5                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3 H          C.sub.3 H.sub.5                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3 6-CH.sub.3 C.sub.3 H.sub.5                                                                        CH.sub.3                                 Cl        Cl       H          C.sub.5 H.sub.9                                                                        CH.sub.3                                 Cl        H        6-Cl       C.sub.5 H.sub.9                                                                        CH.sub.3                                 Cl        H        6-F        C.sub.5 H.sub.9                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3 H          C.sub.5 H.sub.9                                                                        CH.sub.3                                 CH.sub.3  CH.sub.3 6-CH.sub.3 C.sub.5 H.sub.9                                                                        CH.sub.3                                 Cl        Cl       H          C.sub.6 H.sub.11                                                                       CH.sub.3                                 Cl        H        6-Cl       C.sub.6 H.sub.11                                                                       CH.sub.3                                 Cl        H        6-F        C.sub.6 H.sub.11                                                                       CH.sub.3                                 CH.sub.3  CH.sub.3 H          C.sub.6 H.sub.11                                                                       CH.sub.3                                 CH.sub.3  CH.sub.3 6-CH.sub.3 C.sub.6 H.sub.11                                                                       CH.sub.3                                 ______________________________________                                          A* =-                                                                          ##STR127##                                                                    -  The following compounds of the formula (Ie) may be mentioned                 individually in addition to the compounds mentioned in the Preparation      Examples:

                                      TABLE 5                                      __________________________________________________________________________      ##STR128##                       (Ie)                                         A*  B   X   Y  Z.sub.n                                                                            L R.sup.4                                                                             R.sup.5                                              __________________________________________________________________________     C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                             ##STR129##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                             ##STR130##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                             ##STR131##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                             ##STR132##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                             ##STR133##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                             ##STR134##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                             ##STR135##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                             ##STR136##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                             ##STR137##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                             ##STR138##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                             ##STR139##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                             ##STR140##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                             ##STR141##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                             ##STR142##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                             ##STR143##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                             ##STR144##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                             ##STR145##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                             ##STR146##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                      ##STR147##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                      ##STR148##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                      ##STR149##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     itC.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                      ##STR150##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                      ##STR151##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                      ##STR152##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                      ##STR153##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                      ##STR154##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                      ##STR155##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                      ##STR156##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                      ##STR157##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                      ##STR158##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                      ##STR159##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                      ##STR160##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                      ##STR161##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                      ##STR162##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                      ##STR163##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                      ##STR164##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                            ##STR165##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                            ##STR166##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                            ##STR167##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                            ##STR168##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                            ##STR169##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                            ##STR170##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                            ##STR171##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                            ##STR172##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                            ##STR173##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                            ##STR174##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                            ##STR175##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                            ##STR176##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                            ##STR177##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                            ##STR178##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                            ##STR179##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                            ##STR180##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                            ##STR181##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                            ##STR182##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                     ##STR183##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                     ##STR184##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                     ##STR185##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                     ##STR186##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                     ##STR187##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                     ##STR188##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                     ##STR189##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                     ##STR190##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                     ##STR191##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC2H5                                                                               CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                     ##STR192##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                     ##STR193##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                     ##STR194##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                     ##STR195##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                     ##STR196##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                     ##STR197##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                     ##STR198##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                     ##STR199##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                     ##STR200##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         O OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                      ##STR201##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                      ##STR202##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                      ##STR203##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                      ##STR204##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                      ##STR205##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                      ##STR206##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5O                                     C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                      ##STR207##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                      ##STR208##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                      ##STR209##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5O                                     C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                      ##STR210##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                      ##STR211##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                      ##STR212##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                      ##STR213##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                      ##STR214##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                      ##STR215##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                      ##STR216##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                      ##STR217##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                      ##STR218##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S C.sub.2 H.sub.5                                                                     t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                             ##STR219##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                             ##STR220##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                             ##STR221##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                             ##STR222##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                             ##STR223##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                             ##STR224##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.2 H.sub.5O                                     C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                             ##STR225##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                             ##STR226##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                             ##STR227##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                             ##STR228##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                             ##STR229##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                             ##STR230##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S C.sub.2 H.sub.5                                                                     C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                             ##STR231##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                             ##STR232##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                             ##STR233##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                             ##STR234##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                             ##STR235##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                             ##STR236##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S CH.sub.3                                                                            t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                            ##STR237##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                            ##STR238##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                            ##STR239##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                            ##STR240##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                            ##STR241##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                            ##STR242##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.2 H.sub.5O                                     C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                            ##STR243##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                            ##STR244##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                            ##STR245##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                            ##STR246##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                            ##STR247##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                            ##STR248##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                            ##STR249##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                            ##STR250##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                            ##STR251##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                            ##STR252##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                            ##STR253##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                            ##STR254##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OCH.sub.3                                                                           t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                     ##STR255##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                     ##STR256##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                     ##STR257##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                     ##STR258##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                     ##STR259##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                     ##STR260##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                     ##STR261##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                     ##STR262##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                     ##STR263##                                          C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.3 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                     ##STR264##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                     ##STR265##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                     ##STR266##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           Cl  Cl H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                     ##STR267##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                     ##STR268##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                     ##STR269##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          H   S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    CH.sub.3 O                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 O                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 O                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 O                         C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                     ##STR270##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                     ##STR271##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                     ##STR272##                                          C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    CH.sub.3 S                                           C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.2 H.sub.5 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    C.sub.3 H.sub.7 S                                    C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.3 H.sub.7 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    i-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    s-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 S                                  C.sub.6 H.sub.11                                                                   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         S OC.sub.2 H.sub.5                                                                    t-C.sub.4 H.sub.9 CH.sub.2 S                         __________________________________________________________________________      A* =-                                                                          ##STR273##                                                                     ##STR274##                                                                     ##STR275##                                                                    -  The following compounds of the formula (If) may be mentioned                 individually in addition to the compounds mentioned in the Preparation      Examples:

                  TABLE 6                                                          ______________________________________                                          ##STR276##                   (If)                                             X     Y       Z.sub.n  A*     B     E                                          ______________________________________                                         Cl    Cl      H        C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             Na                                         Cl    H       6-Cl     C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             Na                                         Cl    H       6-F      C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             Na                                         CH.sub.3                                                                             CH.sub.3                                                                               H        C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             Na                                         CH.sub.3                                                                             CH.sub.3                                                                               6-CH.sub.3                                                                              C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             Na                                         Cl    Cl      H        C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             Na                                         Cl    H       6-Cl     C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             Na                                         Cl    H       6-F      C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             Na                                         CH.sub.3                                                                             CH.sub.3                                                                               H        C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             Na                                         CH.sub.3                                                                             CH.sub.3                                                                               6-CH.sub.3                                                                              C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             Na                                         Cl    Cl      H        C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             Na                                         Cl    H       6-Cl     C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             Na                                         Cl    H       6-F      C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             Na                                         CH.sub.3                                                                             CH.sub.3                                                                               H        C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             Na                                         CH.sub.3                                                                             CH.sub.3                                                                               6-CH.sub.3                                                                              C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             Na                                         Cl    Cl      H        C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    H       6-Cl     C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    H       6-F      C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                CH.sub.3                                                                             CH.sub.3                                                                               H        C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                CH.sub.3                                                                             CH.sub.3                                                                               6-CH.sub.3                                                                              C.sub.3 H.sub.5                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    Cl      H        C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    H       6-Cl     C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    H       6-F      C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                CH.sub.3                                                                             CH.sub.3                                                                               H        C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                CH.sub.3                                                                             CH.sub.3                                                                               6-CH.sub.3                                                                              C.sub.5 H.sub.9                                                                       CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    Cl      H        C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    H       6-Cl     C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                Cl    H       6-F      C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                CH.sub.3                                                                             CH.sub.3                                                                               H        C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                CH.sub.3                                                                             CH.sub.3                                                                               6-CH.sub.3                                                                              C.sub.6 H.sub.11                                                                      CH.sub.3                                                                             (CH.sub.3).sub.2 CHNH.sub.3                ______________________________________                                          ##STR277##                                                                    -  The following compounds of the formula (Ig) may be mentioned                 individually in addition to the compounds mentioned in the preparation      Examples:

                  TABLE 7                                                          ______________________________________                                          ##STR278##                   (Ig)                                             X     Y      Z.sub.n A*    B      R.sup.6 R.sup.7                              ______________________________________                                         Cl    Cl     H       C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    H      6-Cl    C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    H      6-F     C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             CH.sub.3                                                                             CH.sub.3                                                                              H       C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             CH.sub.3                                                                             CH.sub.3                                                                              6-CH.sub.3                                                                             C.sub.3 H.sub.5                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    Cl     H       C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    H      6-Cl    C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    H      6-F     C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             CH.sub.3                                                                             CH.sub.3                                                                              H       C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             CH.sub.3                                                                             CH.sub.3                                                                              6-CH.sub.3                                                                             C.sub.5 H.sub.9                                                                      CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    Cl     H       C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    H      6-Cl    C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    H      6-F     C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             CH.sub.3                                                                             CH.sub.3                                                                              H       C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             CH.sub.3                                                                             CH.sub.3                                                                              6-CH.sub.3                                                                             C.sub.6 H.sub.11                                                                     CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                             Cl    Cl     H       C.sub.3 H.sub.5                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    H      6-Cl    C.sub.3 H.sub.5                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    H      6-F     C.sub.3 H.sub.5                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              CH.sub.3                                                                             CH.sub.3                                                                              H       C.sub.3 H.sub.5                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              CH.sub.3                                                                             CH.sub.3                                                                              6-CH.sub.3                                                                             C.sub.3 H.sub.5                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    Cl     H       C.sub.5 H.sub.9                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    H      6-Cl    C.sub.5 H.sub.9                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    H      6-F     C.sub.5 H.sub.9                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              CH.sub.3                                                                             CH.sub.3                                                                              H       C.sub.5 H.sub.9                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              CH.sub.3                                                                             CH.sub.3                                                                              6-CH.sub.3                                                                             C.sub.5 H.sub.9                                                                      CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    Cl     H       C.sub.6 H.sub.11                                                                     CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    H      6-Cl    C.sub.6 H.sub.11                                                                     CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              Cl    H      6-F     C.sub.6 H.sub.11                                                                     CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              CH.sub.3                                                                             CH.sub.3                                                                              H       C.sub.6 H.sub.11                                                                     CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              CH.sub.3                                                                             CH.sub.3                                                                              6-CH.sub.3                                                                             C.sub.6 H.sub.11                                                                     CH.sub.3                                                                            (CH.sub.2).sub.2O(CH.sub.2).sub.2              ______________________________________                                          ##STR279##                                                                    -  If, according to process (A)                                                 N-2,4-dichlorophenylacetyl-2-cyclohexylalanine ethyl ester is used, the      course of the process according to the invention can be represented by the      following equation:      ##STR280##      If, according to process (B) (variant α),      3-(2,4,6-trimethylphenyl)-5-cyclopropyl-5-methyl-pyrrolidine-2,4-dione and      pivaloyl chloride are used as starting substances, the course of the      process according to the invention can be represented by the following      equation:      ##STR281##      If, according to process B (variant β),      3-(2,4,6-trimethylphenyl)-5-cyclopentyl-5-ethyl-pyrrolidine-2,4-dione and      acetic anhydride are used as starting compounds, the course of the process      according to the invention can be represented by the following equation:      ##STR282##      If, according to process (C),      3-(2,4,6-trimethylphenyl)-5-[(4-methyl)-cyclohexyl]-5-methyl-pyrrolidine-2     ,4-dione and ethoxyethyl chloroformate are used as starting compounds, the      course of the process according to the invention can be represented by the      following equation.      ##STR283##      If, according to process (D.sub.α),      3-(2,4,6-trimethylphenyl)-5-cyclopentyl-5-methyl-pyrrolidine-2,4-dione and      methyl chloromonothioformate are used as starting materials, the course of      the reaction can be represented as follows:      ##STR284##      If, according to process (D.sub.β),      3-(2,4,6-trimethylphenyl)-5-[(3-methyl)-cyclohexyl]-5-ethyl-pyrrolidn-2,4-     dione, carbon disulphide and methyl iodide are used as starting components,      the course of the reaction can be represented as follows:      ##STR285##      If, according to process (E),      3-(2,4,6-trimethylphenyl)-5-cyclohexyl-5-trifluoromethyl-pyrrolidine-2,4-d     ione and methanesulphonyl chloride are used as starting material, the      course of the reaction can be represented by the following equation:      ##STR286##      If, according to process (F),      3-(2,4-dimethylphenyl)-5-cyclopropyl-5-methyl-pyrrolidine-2,4-dione and      2,2,2-trifluoroethyl methanethio-chlorophosphonate are used as starting      materials, the course of the reaction can be represented by the following      equation:      ##STR287##      If, according to process (G),      3-(2,4,6-trimethylphenyl)-5-cyclohexyl-5-butyl-pyrrolidine-2,4-dione and      NaOH are used as reactants, the course of the process according to the      invention can be represented by the following equation:      ##STR288##      If, according to process      (H.sub.α),3-(2,4,6-trimethylphenyl)-5-[(4-methoxy)-cyclohexyl]-5-met     hyl-pyrrolidine-2,4-dione and ethyl isocyanate are used as starting      materials, the course of the reaction can be represented by the following      equation:      ##STR289##      If, according to process (H.sub.β),      3-(2,4,6-trimethylphenyl)-5-cyclopentyl-5-methyl-pyrrolidine-2,4-dione and      dimethylcarbamoyl chloride are used as starting materials, the course of      the reaction can be represented by the following equation:      ##STR290##      Some of the compounds of the formula (II)      ##STR291##      in which A, B, X, Y, Z, n and R.sup.8 have the abovementioned meaning,

which are required as starting substances in process (A) according to the invention, are known and the subject of a patent application by the applicant company which has not been disclosed to date (P 42 36 400).

For example, acyl-amino acid esters of the formula (II) are obtained when

amino acid derivatives of the formula (XIV) ##STR292## in which R^(9') represents hydrogen (XIVa) and alkyl (XIVb) and

A and B have the abovementioned meaning,

are acylated with phenylacetyl halides of the formula

(xv) ##STR293## in which X, Y, Z and n have the abovementioned meaning and

Hal represents chlorine or bromine,

(Chem. Reviews 52, 237-416 (1953); Bhattacharya, Indien J. Chem. 6, 341-5, 1968) or when acylamino acids of the formula (IIa) ##STR294## in which A, B, X, Y, Z and n have the abovementioned meaning and

R⁹ represents hydrogen,

are esterified (them. Ind. (London) 1568 (1968)).

Furthermore, the starting substances of the formula (II) ##STR295## in which A, B, X, Y, Z, n and R⁸ have the abovementioned meaning,

and which are used in the above process (A), can be prepared when aminonitriles of the formula (XVI) ##STR296## in which A and B have the abovementioned meaning,

are reacted with phenylacetyl halides of the formula (XV) ##STR297## in which X, Y, Z and n have the abovementioned meaning and

Hal represents chlorine or bromine,

to give compounds of the formula (XVII) ##STR298## in which A, B, X, Y, Z and n have the abovementioned meaning,

which are subsequently subjected to alcoholysis in sulphuric acid.

Some of the compounds of the formula (XVII) are also known and the subject of a patent application by the applicant company which has not been disclosed to date (P 42 36 400).

The following compounds of the formula (II) may be mentioned by way of example, in addition to the intermediates mentioned in the Preparation Examples, but not by way of limitation:

N-(2,4-dichlorophenylacetyl)-2-cyclopropyl-alanine methyl ester,

N-(2,4-dichlorophenylacetyl)-2-cyclohexyl-alanine methyl ester,

N-(2,4-dichlorophenylacetyl)-2-cyclopropyl-alanine ethyl ester,

N-(2,4-dichlorophenylacetyl)-2-cyclohexyl-alanine ethyl ester,

N-(2,6-dichlorophenylacetyl)-2-cyclopropyl-alanine methyl ester,

N-(2,6-dichlorophenylacetyl)-2-cyclohexyl-alanine methyl ester,

N-(2,6-dichlorophenylacetyl)-2-cyclopropyl-alanine ethyl ester,

N-(2,6-dichlorophenylacetyl)-2-cyclohexyl-alanine ethyl ester,

N-(2-chloro-6-fluoro-phenyl-acetyl)-2-cyclopropyl-alanine methyl ester,

N-(2-chloro-6-fluorophenylacetyl)-2-cyclohexyl-alanine methyl ester,

N-(2-chloro-6-fluorophenylacetyl)-2-cyclopropyl-alanine ethyl ester,

N-(2-chloro-6-fluorophenylacetyl)-2-cyclohexyl-alanine ethyl ester,

N-(2,4,6-trimethylphenylacetyl)-2-cyclopropyl-alanine methyl ester,

N-(2,4,6-trimethylphenylacetyl)-2-cyclohexyl-alanine methyl ester,

N-(2,4,6-trimethylphenylacetyl)-2-cyclopropyl-alanine ethyl ester,

N-(2,4,6-trimethylphenylacetyl)-2-cyclohexyl-alanine ethyl ester,

N-(2,4-dimethylphenylacetyl)-2-cyclopropyl-alanine methyl ester,

N-(2,4-dimethylphenylacetyl)-2-cyclohexyl-alanine methyl ester,

N-(2,4-dimethylphenylacetyl)-2-cyclopropyl-alanine ethyl ester,

N-(2,4-dimethylphenylacetyl)-2-cyclohexyl-alanine ethyl ester,

Compounds of the formula (IIa) can be obtained, for example, from the phenylacetyl halides of the formula (XV) and amino acids of the formula (XIVa) by the method of Schotten-Baumann (Organikum [Laboratory Course in Organic Chemistry], 9th edition, 446 (1970) VEB Deutscher Verlag der Wissenschaften, Berlin).

The acid halides of the formula (III), carboxylic anhydrides of the formula (IV), chloroformic esters or chloroformic thioesters of the formula (V), chloromonothioformic esters or chlorodithioformic esters of the formula (VI), alkyl halides of the formula (VII), sulphonyl chlorides of the formula (VIII), phosphorus compounds of the formula (IX) and metal hydroxides or amines of the formula (X) and (XI) and isocyanates or carbamoyl chloride of the formula (XIII), all of which are furthermore required as starting substances for carrying out processes (B), (C), (D), (E), (F), (G) and (H) according to the invention, are generally known compounds of organic or inorganic chemistry.

Process (A) is characterized in that compounds of the formula (II), in which A, B, X, Y, Z, n and R⁸ have the abovementioned meaning, are subjected to an intramolecular condensation reaction in the presence of bases.

Diluents which can be employed in process (A) according to the invention are all inert organic solvents. The following can preferably be used: hydrocarbons, such as toluene and xylene, furthermore ethers, such as dibutyl ether, tetrahydrofuran, dioxane, glycol dimethyl ether and diglycol dimethyl ether, moreover polar solvents, such as dimethyl sulphoxide, sulpholane, dimethylformamide and N-methyl-pyrrolidone, and also alcohols, such as methanol, ethanol, propanol, isopropanol, butanol, iso-butanol and tert.-butanol.

Bases (deprotonating agents) which can be employed when carrying out process (A) according to the invention are all customary proton acceptors. The following can preferably be used: alkali metal oxides, alkali metal hydroxides, alkali metal carbonates, alkaline earth metal oxides, alkaline earth metal hydroxides and alkaline earth metal carbonates, such as sodium hydroxide, potassium hydroxide, magnesium oxide, calcium oxide, sodium carbonate, potassium carbonate and calcium carbonate, sodium carbonate, potassium carbonate and calcium carbonate, all of which can also be employed in the presence of phase transfer catalysts, such as, for example, triethylbenzylammonium chloride, tetrabutylammonium bromide, Adogen 464 or TDA 1^(*)). Alkali metals such as sodium or potassium can furthermore be employed. Other substances which can be employed are alkali metal amides, alkali metal hydrides, alkaline earth metal amides and alkaline earth metal hydrides, such as sodium amide, sodium hydride and calcium hydride, moreover also alkali metal alcoholates, such as sodium methylate, sodium ethylate and potassium tert.-butylate.

When carrying out process (A) according to the invention, the reaction temperatures can be varied within a substantial range. In general, the process is carried out at temperatures between 0° C. and 250° C., preferably between 50° C. and 150° C.

In general, process (A) according to the invention is carried out under atmospheric pressure.

When carrying out process (A) according to the invention, the reactants of the formulae (II) and the deprotonating bases are generally employed in about twice the equimolar amounts. However, it is also possible to use the one or the other reactant in a larger excess (up to 3 mol).

Process (Bα) is characterized in that compounds of the formula (Ia) are reacted with carboxylic halides of the formula (III).

If the acid halides are used in process (Bα) according to the invention, then diluents which can be employed are all solvents which are inert towards these compounds. The following can preferably be used: hydrocarbons, such as benzine, benzene, toluene, xylene and tetralin, furthermore halogenohydrocarbons, such as methylene chloride, chloroform, carbon tetrachloride, chlorobenzene and o-dichlorobenzene, moreover ketones, such as acetone and methyl isopropyl ketone, furthermore ethers, such as diethyl ether, tetrahydrofuran and dioxane, in addition carboxylic esters, such as ethyl acetate, and also strongly polar solvents, such as dimethyl sulphoxide and sulpholane. If the acid halide is sufficiently stable to hydrolysis, the reaction can also be carried out in the presence of water.

If the corresponding carboxylic halides are used, then acid-binding agents which are suitable for the reaction in accordance with process (Bα) according to the invention are all customary acid acceptors. The following can preferably be used: tertiary amines, such as triethylamine, pyridine, diazabicyclooctane (DABCO), diazabicycloundecene (DBU), diazabicyclononene (DBN), Hunig base and N,N-dimethyl-aniline, furthermore alkaline earth metal oxides, such as magnesium oxide and calcium oxide, moreover alkali metal carbonates and alkaline earth metal carbonates, such as sodium carbonate, potassium carbonate and calcium carbonate, and also alkali metal hydroxides, such as sodium hydroxide and potassium hydroxide.

When carrying out process (Bα) according to the invention, the reaction temperatures can also be varied within a substantial range, which also applies if carboxylic halides are used. In general, the process is carried out at temperatures between -20° C. and +150° C., preferably between 0° C. and 100° C.

When carrying out process (Bα) according to the invention, the starting substances of the formula (Ia) and the carboxylic halide of the formula (III) are generally used in approximately equivalent amounts. However, it is also possible to employ the carboxylic halide in a larger excess (up to 5 mol). Working-up is carried out by customary methods.

Process (Bβ) is characterized in that compounds of the formula (Ia) are reacted with carboxylic anhydrides of the formula (IV).

If, in process (Bβ) according to the invention, carboxylic anhydrides are used as reactant of the formula (IV), then diluents which can preferably be used are those which are also preferably suitable when acid halides are used. Besides, a carboxylic anhydride employed in excess can also simultaneously act as the diluent.

When carrying Out process (Bβ) according to the invention, the reaction temperatures can be varied within a substantial range, which also applies if carboxylic anhydrides are used. In general, the process is carried out at temperatures between -20° C. and +150° C., preferably between 0° C. and 100° C.

When carrying out the process according to the invention, the starting substances of the formula (Ia) and the carboxylic anhydride of the formula (IV) are generally used in approximately equivalent amounts. However, it is also possible to employ the carboxylic anhydride in a larger excess (up to 5 mol). Working-up is carried out by customary methods.

In general, a procedure is followed in which diluent and excess carbolyxic anhydride as well as the carboxylic acid which forms are removed by distillation or by washing with an organic solvent or with water. Process (C) is characterized in that compounds of the formula (Ia) are reacted with chloroformic esters or chloroformic thioesters of the formula (V).

If the corresponding chloroformic esters or chloroformic thioesters are used, then acid-binding agents in the reaction in accordance with process (C) according to the invention are all customary acid acceptors. The following can preferably be used: tertiary amines, such as triethylamine, pyridine, DABCO, DBU, DBA, Hunig base and N,N-dimethyl-aniline, furthermore alkaline earth metal oxides, such as magnesium oxide and calcium oxide, furthermore alkali metal carbonates and alkaline earth metal carbonates, such as sodium carbonate, potassium carbonate and calcium carbonate, and also alkali metal hydroxides, such as sodium hydroxide and potassium hydroxide.

If the chloroformic esters or chloroformic thioesters ere used, then diluents which can be employed in process (C) according to the invention are all solvents which are inert towards these compounds. The following can preferably be used: hydrocarbons, such as benzine, benzene, toluene, xylene and tetralin, furthermore halogenohydrocarbons, such as methylene chloride, chloroform, carbon tetrachloride, chlorobenzene and o-dichlorobenzene, furthermore ketones, such as acetone and methyl isopropyl ketone, moreover ethers, such as diethyl ether, tetrahydrofuran and dioxane, in addition carboxylic esters, such as ethyl acetate, and also strongly polar solvents, such as dimethyl sulphoxide and sulpholane.

If the chloroformic esters or chloroformic thioesters are used as carboxylic acid derivatives of the formula (V), then the reaction temperatures can be varied within a substantial range when carrying out process (C) according to the invention. If the process is carried out in the presence of a diluent and of an acid-binding agent, then the reaction temperatures are generally between -20° C. and 100° C., preferably between 0° C and 50° C.

Process (C) according to the invention is generally carried out under atmospheric pressure.

When carrying out process (C) according to the invention, the starting substances of the formula (Ia) and the chloroformic ester or chloroformic thioester of the formula (V) in question are generally used in approximately equivalent amounts. However, it is also possible to employ one or the other reactant in a larger excess (up to 2 mol). Working-up is then carried out by customary methods. In general, a procedure is followed in which precipitated salts are removed and the reaction mixture which remains is concentrated by stripping off the diluent.

In preparation process (D), approximately 1 mol of chloromonothioformic ester or chlorodithioformic ester of the formula (VI) is reacted at 0° to 120° C., preferably at 20° to 60° C., per mole of starting compound of the formula (Ia).

Suitable diluents which may be added are all inert polar organic solvents, such as ethers, amides, sulphones or sulphoxides.

Dimethyl sulphoxide, tetrahydrofuran, dimethylformamide and dimethyl sulphide are preferably employed.

If, in a preferred embodiment, the enolate salt of the compound Ia is prepared by adding strong deprotonating agents, such as, for example, sodium hydride or potassium tertiary butylate, the further addition of acid-binding agents can be dispensed with.

If acid-binding agents are employed, then suitable substances are customary inorganic or organic bases, sodium hydroxide, sodium carbonate, potassium carbonate, pyridine and triethylamine being mentioned by way of example.

The reaction can be carried out under atmospheric pressure or under increased pressure; it is preferably carried out under atmospheric pressure. Working-up is carried out by customary methods.

In preparation process (D.sub.β), the equimolar amount, or an excess, of carbon disulphide is added per mole of starting compound of the formula (Ia). This process is preferably carried out at temperatures from 0° to 50° C. and, in particular, at 20° to 30° C.

Frequently, it is expedient to first prepare the corresponding salt from the compound of the formula (Ia) by adding a deprotonating agent (such as, for example, potassium tertiary butylate or sodium hydride). The compound (Ia) is reacted with carbon disulphide until the formation of the intermediate is complete, for example after stirring for several hours at room temperature.

The further reaction with the alkyl halide of the formula (VII) is preferably carried out at 0° to 70° C., in particular at 20+20 to 50° C. At least the equimolar amount of alkyl halide is employed.

The process is carried out under atmospheric pressure or under increased pressure, preferably under atmospheric pressure.

Again, working-up is carried out by customary methods.

In preparation process (E), approximately 1 mol of sulphonyl chloride (VIII) is reacted per mole of starting compound of the formula (Ia) at -20° to 150° C., preferably at 0° to 70° C.

Suitable diluents which may be added are all inert polar organic solvents, such as ethers, amides, nitriles, sulphones, sulphoxides or halogenated hydrocarbons, such as methylene chloride.

Dimethyl sulphoxide, tetrahydrofuran, dimethylformamide, dimethyl sulphide and methylen chloride are preferably employed.

If, in a preferred embodiment, the enolate salt of the compound Ia is prepared by adding strong deprotonating agents (such as, for example, sodium hydride or potassium tertiary butylate), the further addition of acid-binding agents can be dispensed with.

If acid-binding agents are employed, then suitable substances are customary inorganic or organic bases, sodium hydroxide, sodium carbonate, potassium carbonate, pyridine and triethylamine being mentioned by way of example.

The reaction can be carried out under atmospheric pressure or under increased pressure, it is preferably carried out under atmospheric pressure. Working-up is carried out by customary methods.

To obtain compounds of the structure (Ie) 1 to 2, preferably 1 to 1.3 mol of the phosphorus compound of the formula (IX) are reacted in preparation process (F) per mole of the compound (Ia) at temperatures between -40° C. and 150° C., preferably between -10° and 110° C.

Suitable diluents which my be added are all inert, polar organic solvents, such as ethers, amides, nitriles, alcohols, sulphides, sulphones, sulphoxides and the like.

Acetonitrile, dimethyl sulphoxide, tetrahydrofuran, dimethylformamide or methylene chloride are preferably employed.

Suitable acid-binding agents which may be added are customary inorganic or organic bases, such as hydroxides or carbonates. Examples which may be mentioned are sodium hydroxide, sodium carbonate, potassium carbonate, pyridine and triethylamine.

The reaction can be carried out under atmospheric pressure or under increased pressure, it is preferably carried out under atmospheric pressure. Working-up is carried out by customary methods of organic chemistry. The end products obtained are preferably purified by crystallization, chromatography or by so-called "incipient distillation", i.e. removal of the volatile components in vacuo.

Process (G) is characterized in that compounds of the formula (Ia) are reacted with metal hydroxides (X) or amines (XI).

Diluents which can be employed in the process according to the invention are, preferably, ethers, such as tetrahydrofuran, dioxane or diethyl ether, or else alcohols, such as methanol, ethanol, isopropanol, but also water. Process (G) according to the invention is preferably carried out under atmospheric pressure. The reaction temperatures are generally between -20° C. and 100° C., preferably between 0° C. and 50° C.

In preparation process (H.sub.α), approximately 1 mol of isocyanate, or isothiocyanate, of the formula (XII) is reacted per mole of starting compound of the formula (Ia) at 0° to 100° C., preferably at 20° to 50° C.

Suitable diluents which may be added are all inert organic solvents, such as ethers, amides, nitriles, sulphones or sulphoxides.

If appropriate, catalysts may be added to accelerate the reaction. Catalysts which are very advantageously employed are organotin compounds, such as, for example, dibutyltin dilaurate. The process is preferably carried out under atmospheric pressure.

In preparation process (H.sub.β), approximately 1 mol of carbamoyl chloride of the formula (XIII) is reacted per mole of starting compound of the formula (Ia) at 0° to 150° C., preferably at 20° to 70° C.

Suitable diluents which may be added are all inert polar organic solvents, such as ethers, amides, sulphones or sulphoxides.

Dimethyl sulphoxide, tetrahydrofuran, dimethylformamide or methylene chloride are preferably employed.

If, in a preferred embodiment, the enolate salt of the compound (Ia) is prepared by adding strong deprotonating agents (such as, for example, sodium hydride or potassium tertiary butylate), the further addition of acid-binding agents can be dispensed with.

If acid-binding agents are employed, then suitable substances are customary inorganic or organic bases, sodium hydroxide, sodium carbonate, potassium carbonate, triethylamine or pyridine being mentioned by way of example.

The reaction can be carried out under atmospheric pressure or under increased pressure, it is preferably carried out under atmospheric pressure. Working-up is carried out by customary methods.

The active compounds are suitable for combating animal pests, preferably arthropods and nematodes, in particular insects and arachnids, which occur in agriculture, in forests, in the protection of stored products and of materials, and in the hygiene sector. They are active against normally sensitive and resistant species and against all or individual development stages. The abovementioned pests include:

From the order of the Isopoda, for example, Oniscus asellus, Armadillidium vulgare and Porcellio scaber.

From the order of the Diplopoda, for example, Blaniulus guttulatus From the order of the Chilopoda, for example, Geophilus carpophagus and Scutigera spec. From the order of the Symphyla, for example, Scutigerella immaculata. From the order of the Thysanura, for example, Lepisma saccharina. From the order of the Collembola, for example, Onychiurus armatus.

From the order of the Orthoptera, for example, Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus differentialis and Schistocerca gregaria.

From the order of the Dermaptera, for example, Forficula auricularia. From the order of the Isoptera, for example, Reticulitermes spp.

From the order of the Anoplura, for example, Phylloxera vastatrix, Pemphigus spp., Pediculus humanus corporis, Haematopinus spp. and Linognathus spp. From the order of the Mallophaga, for example, Trichodectes spp. and Damalinea spp. From the order of the Thysanoptera, for example, Hercinohrips femoralis and Thrips tabaci. From the order of the Heteroptera, for example, Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus and Triatoma spp.

From the order of the Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Doralis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp. Psylla spp.

From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella maculipennis, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp. Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Spodoptera exigua, Mamestra brassicae, Panolis flammea, Prodenia litura, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima and Tortrix viridana.

From the order of the Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Acanthoscelides obtectus, Hylotrupes byjulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis and Costelytra zealandica.

From the order of the Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis and Vespa spp.

From the order of the Diptera, for example, Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae and Tipula paludosa.

From the order of the Siphonaptera, for example, Xenopsylla cheopis and Ceratophyllus spp. From the order of the Arachnida, for example, Scorpio maurus and Latrodectus mactans.

From the order of the Acarina, for example, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp. and Tetranychus spp.

The active compounds according to the invention are not only active against plant, hygiene and stored product pests, but also, in the veterinary medicine sector, against animal parasites (ectoparasites and endoparasites), such as scaly ticks, Argasidae, scab mites, Trombidae, flies (stinging and sucking), parasitic fly larvae, lice, hair lice, bird lice, fleas and endoparasitic worms. For example, they show an outstanding activity against Lucilia cuprina larvae.

The active compounds according to the invention are distinguished by a powerful insecticidal and acaricidal activity.

They can be employed particularly successfully for combating plant-injurious mites, such as, for example, against the greenhouse red spider mite (Tetranychus urticae).

The active compounds according to the invention also have a leaf-acting insecticidal activity.

The active compounds according to the invention can also be also used as defoliants, desiccants, agents for destroying broad-leaved plants and, especially, as weed-killers. By weeds, in the broadest sense, there are to be understood all plants which grow in locations where they are undesired. Whether the substances according to the invention act as total or selective herbicides depends essentially on the amount used.

The active compounds according to the invention can be used, for example, in connection with the following plants:

Dicotyledon weeds of the genera: Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduus, Sonchus, Solanum, Rorippa, Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus and Taraxacum.

Dicotyledon cultures of the genera: Gossypium, Glycine, Beta, Daucus, Phaseolus, Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, Cucumis and Cucurbita.

Monocotyledon weeds of the genera: Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus and Apera.

Monocotyledon cultures of the genera: Oryza, Zea, Triticum, Hordeum, Avena, Secale, Sorghum, Panicum, Saccharum, Ananas, Asparagus and Allium.

However, the use of the active compounds according to the invention is in no way restricted to these genera, but also extends in the same manner to other plants.

The compounds are suitable, depending on the concentration, for the total combating of weeds, for example on industrial terrain and rail tracks, and on paths and squares with or without tree plantings. Equally, the compounds can be employed for combating weeds in perennial cultures, for example afforestations, decorative tree plantings, orchards, vineyards, citrus groves, nut orchards, banana plantations, coffee plantations, tea plantations, rubber plantations, oil palm plantations, cocoa plantations, soft fruit plantings and hopfields, in lawns, turf and pasture-land, and for the selective combating of weeds in annual cultures.

The active compounds according to the invention are highly suitable for selectively combating monocotyIedon weeds in dicotyledon cultures either pre- or post-emergence. For example, they can be used very successfully for combating swedes in soya beans or sugar beet. The active compounds can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusting agents, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with active compound, and very fine capsules in polymeric substances.

These formulations are produced in a known manner, for example by mixing the active compounds with extenders, that is liquid solvents and/or solid carriers, optionally with the use of surface-active agents, that is emulsifying agents and/or dispersing agents and/or foam-forming agents.

In the case of the use of water as an extender, organic solvents can, for example, also be used as auxiliary solvents. As liquid solvents, there are suitable in the main: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulphoxide, as well as water.

As solid carriers there are suitable: for example ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as highly disperse silica, alumina and silicates, as solid carriers for granules there are suitable: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, as well as synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; as emulsifying and/or foam-forming agents there are suitable: for example non-ionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulphonates, alkyl sulphates, arylsulphonates as well as albumen hydrolysis products; as dispersing agents there are suitable: for example lignin-sulphite waste liquors and methylcellulose.

Adhesives such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latexes, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, as well as natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids, can be used in the formulations. Further additives can be mineral and vegetable oils.

It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

The formulations in general contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.

For combating weeds, the active compounds according to the invention, as such or in the form of their formulations, can also be used as mixtures with known herbicides, finished formulations or tank mixes being possible.

Suitable herbicides for the mixtures are known herbicides, such as, for example, 1-amino-6-ethylthio-3-(2,2dimethylpropyl)-1,3,5-triazine-2,4(1H, 3H)-dione (AMETHYDIONE) or N-(2-benzothiazolyl)-N,N'-dimethylurea (METABENZTHIAZURON) for combating weeds in cereals; 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5-(4H)-one (METAMITRON) for combating weeds in sugar beet, and 4-amino-6-(1,1-dimethylethyl)-3-methylthio-1,2,4-triazin-5(4H)-one (METRIBUZIN) for combating weeds in soya beans. Other suitable herbicides are 2,4-dichlorophenoxyacetic acid (2,4-D); 4-(2,4-dichlorophenoxy) butyric acid (2,4-DB); 2,4-dichlorophenoxypropionic acid (2,4-DP); 3-isopropyl-2, 1, 3-benzothiadiazin-4-one-2,2-dioxide (BENTAZONE); methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate (BIFENOX); 3,5-dibromo-4-hydroxy-benzonitrile (BROMOXYNIL); 2-chloro-N-{[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-amino]-carbonyl}-benzenesulphonamide (CLORSULFURON); 2-[4-(2,4-dichlorophenoxy)-phenoxy]propionic acid, its methyl or its ethyl ester (DICLOFOPMETHYL); 4-amino-6-t-butyl-3-ethylthio-1,2,4-triazin-5(4H)-one (ETHIOZIN); 2-{4-[(6-chloro-2-benzoxazolyl)-oxy]-phenoxy}-propanoic acid, its methyl or its ethyl ester (FENOXAPROP); [(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)-oxy]-acetic acid or its 1-methylheptyl ester (FLUROXYPYR); methyl 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H- imidazol-2-yl]-4 (5) -methylbenzoate (IMAZAMETHABENZ); 3,5-diiodo-4-hydroxybenzonitrile (IOXYNIL); N,N-dimethyl-N'-(4-isopropylphenyl)urea (ISOPROTURON); (2-methyl-4-chlorophenoxy) acetic acid (MCPA); (4-chloro-2-methylphenoxy)-propionic acid (MCPP); N-methyl-2-(1,3-benzothiazol-2-yloxy) acetanilide (MEFENACET); 2-{[[((4-methoxy-6-methyl-1,3,5-triazin-2-yl)-amino)-carbonyl]-amino]-sulphonyl}-benzoic acid or its methylester (METSULFURON); N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitroaniline (PENDIMETHALIN); 0-(6-chloro-3-phenyl-pyridazin-4-yl) S-octyl thiocarbonate (PYRIDATE); 4-ethylamino-2-t-butylamino-6-methylthio-s-triazine (TERBUTRYNE); and 3-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-amino]-carbonyl]-amino]-sulphonyl]thiophene-2-carboxylic acid (THIAMETURON). Surprisingly, some mixtures also show synergistic action.

Mixtures with i other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellants, plant nutrients and agents which improve soil structure, are also possible.

The active compounds can be used as such, in the form of their formulations or in the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. They are used in the customary manner, for example by watering, spraying, atomizing or scattering.

The active compounds according to the invention can be applied either before or after emergence of the plants.

They can also be incorporated into the soil before sowing.

The amount of active compound used can vary within a substantial range. It depends essentially on the nature of the desired effect. In general, the amounts used are between 0.01 and 10 kg of active compound per hectare of soil surface, preferably between 0.05 and 5 kg per ha.

The preparation and use of the active compounds according to the invention can be seen from the following examples.

PREPARATION EXAMPLES Example (Ia-1) ##STR299##

55.5 g (0.493 mol) of potassium tert.-butylate are heated at reflux temperature in 150 ml of absolute tetrahydrofuran. 83.4 g (0.224 tool) of N-(2,4-dichlorophenylacetyl) 2-cyclohexyl-alanine methyl ester in 450 ml of absolute toluene are added dropwise and the mixture is refluxed for 90 minutes. After the reaction has ended, the batch is brought to room temperature, and 720 ml of water are added. The aqueous phase is separated off, and the toluene phase is extracted using 340 ml of water. The combined aqueous phases are washed with toluene and subsequently treated with 75 ml of concentrated hydrochloric acid at room temperature. The crude product which has precipitated is filtered off with suction, washed and dried.

53.10 g (70% of theory) of 3-(2,4-dichlorophenyl)-5-cyclohexyl-5-methylpyrrolidine-2,4-dione of melting point m.p. 196°-198° C. are obtained.

The end products of the formula (Ia) which are listed below in Table 8 are obtained analogously to Example (Ia-1) and following the general information which can be found in the description for the processes according to the invention:

                  TABLE 8                                                          ______________________________________                                          ##STR300##                   (Ia)                                             Ex.                                     Phylical                               No.:  A          B      X    Y    Z.sub.n                                                                              constant [°C.]                  ______________________________________                                         (Ia-2)                                                                                ##STR301##                                                                               CH.sub.3                                                                              Cl   Cl   H     m.p.: 150                              (Ia-3)                                                                                ##STR302##                                                                               CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                            6-CH.sub.3                                                                           m.p.: >220                             (Ia-4)                                                                                ##STR303##                                                                               CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                            6-CH.sub.3                                                                           m.p.: 223-225                          (Ia-5)                                                                                ##STR304##                                                                               CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                            H     m.p.: 172-173                          ______________________________________                                    

Example (Ib-1) ##STR305##

5.1 g (0.015 mol) of 3-(2,4-dichlorophenyl)-5-cyclohexyl-5-methyl-pyrrolidine-2,4-dione are suspended in 70 ml of absolute dichloromethane and treated with 2.1 ml of triethylamine. 1.58 ml of isobutyryl chloride in 5 ml of absolute dichloromethane are added at 0°-10° C. The end of the reaction is determined by thin-layer chromatography. The mixture is subsequently washed twice using in each case 100 ml of 0.5N sodium hydroxide solution and the organic phase is dried over magnesium sulphate. The residue obtained after evaporation of the solvent is recrystallized from ether/n-hexane 1:5.

4.4 g (72% of theory) of 3-(2,4-dichlorophenyl)-5-cyclohexyl-5-methyl-4-isobutyroxy-Δ3-pyrolin-2-one of melting point m.p. 138°-140° C. are obtained.

The end products of the formula (I-b) which are listed below in Table 9 are obtained analogously to Example (Ib-1) and following the general information for the processes according to the invention:

                                      TABLE 9                                      __________________________________________________________________________      ##STR306##                         (I-b)                                                                      Physical                                       Ex. No.:                                                                             A      B  X   Y  Z.sub.n                                                                            R1   constant [°C.]                          __________________________________________________________________________     (Ib-2)                                                                                ##STR307##                                                                           CH.sub.3                                                                          Cl  Cl H   CH.sub.3                                                                            174-176                                        (Ib-3)                                                                                ##STR308##                                                                           CH.sub.3                                                                          Cl  Cl H   i-C.sub.3 H.sub.7                                                                   180                                            (Ib-4)                                                                                ##STR309##                                                                           CH.sub.3                                                                          Cl  Cl H   t-C.sub.4 H.sub.9                                                                   175                                            (Ib-5)                                                                                ##STR310##                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         CH.sub.3                                                                            209                                            (Ib-6)                                                                                ##STR311##                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         i-C.sub.3 H.sub.7                                                                   166-167                                        (Ib-7)                                                                                ##STR312##                                                                           CH.sub.3                                                                          Cl  Cl H   CH.sub.3                                                                            181-183                                        (Ib-8)                                                                                ##STR313##                                                                           CH.sub.3                                                                          Cl  Cl H   t-C.sub.4 H.sub.9                                                                   161-163                                        (Ib-9)                                                                                ##STR314##                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         CH.sub.3                                                                            233-237                                        (Ib-10)                                                                               ##STR315##                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          6-CH.sub.3                                                                         i-C.sub.3 H.sub.7                                                                   182-184                                        (Ib-11)                                                                               ##STR316##                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H   CH.sub.3                                                                            155                                            (Ib-12)                                                                               ##STR317##                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H   i-C.sub.3 H.sub.7                                                                   153                                            (Ib-13)                                                                               ##STR318##                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H   t-C.sub.4 H.sub.9                                                                   133-135                                        __________________________________________________________________________

Example (Ic-1) ##STR319##

5.1 g (0.015 mol) of 3-(2,4-dichlorophenyl)-5-cyclohexyl-5-methyl-pyrrolidine-2,4-dione are suspended in 70 ml of absolute dichloromethane and the mixture is treated with 2.1 ml of triethylamine. 1.5 ml of ethyl chloroformate in 5 ml of absolute dichloromethane are added at 0°-10° C., and stirring of the batch is continued at room temperature. The end of the reaction is determined by thin-layer chromatography. The mixture is then washed twice using in each case 100 ml of 0.5N sodium hydroxide solution, and the organic phase is dried over magnesium sulphate. The residue obtained after evaporation of the solvent is recrystallized from ether/n-hexane (1:5).

4.6 g (74% of theory) of O-ethyl O-[3-(2,4-dichlorophenyl)-5-cyclohexyl-5-methyl-Δ3-pyrolin-4-yl-2-one] carbonate of melting point m.p. 175°-176° C. are obtained.

The end products of the formula (Ic) which are listed below in Table 10 are obtained analogously to Example (Ic-1) and following the general information for the processes according to the invention:

                                      TABLE 10                                     __________________________________________________________________________      ##STR320##                         (I-c)                                      Ex.                                                                            No.  A      B  X  Y   Z.sub.n                                                                            L M R.sup.2                                                                            m.p. °C.                              __________________________________________________________________________     (Ic-2)                                                                               ##STR321##                                                                           CH.sub.3                                                                          Cl Cl  H   O O C.sub.2 H.sub.5                                                                    140                                          (Ic-3)                                                                               ##STR322##                                                                           CH.sub.3                                                                          Cl Cl  H   O O s-C.sub.4 H.sub.9                                                                  127                                          (Ic-4)                                                                               ##STR323##                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           6-CH.sub.3                                                                         O O C.sub.2 H.sub.5                                                                    143                                          (Ic-5)                                                                               ##STR324##                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           6-CH.sub.3                                                                         O O s-C.sub.4 H.sub.9                                                                  156-157                                      (Ic-6)                                                                               ##STR325##                                                                           CH.sub.3                                                                          Cl Cl  H   O O s-C.sub.4 H.sub.9                                                                  162-163                                      (Ic-7)                                                                               ##STR326##                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           6-CH.sub.3                                                                         O O C.sub.2 H.sub.5                                                                    218-219                                      (Ic-8)                                                                               ##STR327##                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           6-CH.sub.3                                                                         O O s-C.sub.4 H.sub.9                                                                  201                                          (Ic-9)                                                                               ##STR328##                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           6-CH.sub.3                                                                         O S i-C.sub.3 H.sub.7                                                                  133-135                                      (Ic-10)                                                                              ##STR329##                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O O C.sub.2 H.sub.5                                                                    155                                          (Ic-11)                                                                              ##STR330##                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H   O O s-C.sub.4 H.sub.9                                                                   65                                          __________________________________________________________________________

Example (Ie-1) ##STR331##

3g (11 mmol) of 3-(2,4,6-trimethylphenyl)-5-cyclopropyl-5-methyl-pyrrolidine-2,4-dione are suspended in 20 ml of absolute tetrahydrofurane and the mixture is treated with 1.7 ml of triethylamine. 2.2 g of methyl-propylmercaptothiophosphonic acid chloride are added, then the mixture is stirred at 50° C. for 24 hours. The residue obtained after evaporation of the solvent is chromatographed on silica gel using n-hexane/acetone 9/1 as eluent. 1.7 g (37% of theory) of the compound of the formula (Ie-1) of melting point m.p. 143° C. are obtained.

Example (Ie-2) ##STR332##

Analogously the compound of formula (Ie-2) of melting point m.p. 100° C. is obtained.

Example (Ig-1) ##STR333##

4.86 g (0.02 mol) of 3-(2,4,6-trimethylphenyl)-5-cyclopropyl-5-methyl-pyrrolidine-2,4,-dione are suspended in 70 ml of absolute tetrahydrofurane and the mixture is treated with 2.8 ml of triethylamine. 1.84 ml of dimethylcarbamoyl chloride and 20 mg of 4-N,N-dimethylaminopyridine in 5 ml of absolute tetrahydrofurane are added at 0°-10° C. The reaction mixture is refluxed and the end of the reaction is determined by thin-layer chromatography. The residue obtained after evaporation of the solvent is dissolved in CH₂ Cl₂, washed twice using 0.5N sodium hydroxide solution, the organic phase is dried over magnesium sulphate and the solvent is stripped off in vacuo. 3.1 g (45% of theory) of 4-dimethylcarbamoyloxy-5-cyclopropyl-5-methyl-3-(2,4,6-trimethylphenyl)-.DELTA.3-pyrroline-2-one of melting point m.p. 201°-205° C. are obtained.

Example (Ig-2) ##STR334##

Analogously to Example (Ig-1) 4-morpholinocarbamoyloxy-5-cyclopropyl-5-methyl-3-(2,4,6-trimethylphenyl)-Δ3-pyrroline-2-one of melting point m.p. 137°-141° C. are obtained.

Preparation of the starting compounds

Example (II-1) ##STR335##

89.2 g (0.263 mol) of N-(1-cyano-1-methyl-cyclohexylmethyl)-2-(2,4-dichlorophenyl)-acetamide, dissolved in 270 ml of dichloromethane, are added dropwise with stirring and ice-cooling to 128 g (1.31 mol) of concentrated sulphuric acid, during which process the temperature of the reaction mixture rises to 40° C., and, after the addition has ended, stirring is continued for 2 hours at 40° C. until the dichloromethane phase of the reaction mixture has become colourless. 184 ml of absolute methanol are subsequently added dropwise with ice-cooling, during which process the temperature of the reaction mixture rises to 40° C., and stirring is continued for 6 hours at 40°-50° C. For working-up, the reaction mixture is poured into 1500 g of ice, with stirring, and the mixture is extracted using dichloromethane, the combined organic phases are washed using aqueous sodium hydrogencarbonate solution until free from acid and dried over magnesium sulphate, and the solvent is removed in vacuo.

83.6 g (85% of theory) of N-(2,4-dichlorophenyl-acetyl)-2-cyclohexyl-alanine methyl ester of melting point m.p. 107°-108° C. are obtained.

Example (II-2) ##STR336##

Analogously to Example (II-1), N-(2,4-dichlorophenylacetyl)-2-cyclopropyl-alanine methyl ester of melting point m.p. 81° C. is obtained.

Use Examples

In the Use Examples which follow, the compounds listed below were employed as comparison substances: ##STR337## 3-(2,4,6-Trimethylphenyl)-5-methyl-5-isopropyl-4-acetoxy-Δ3-pyrrolin-2-one, disclosed in EP 456,063. ##STR338## 3-(2,4,6-Trimethylphenyl)-5-methyl-5-isopropyl-pyrrolidine-2,4-dione, disclosed in EP 456,063.

Use Example Example A

Pre-emergence test

Solvent: 5 parts by weight of acetone

Emulsifier: 1 part by weight of alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration.

Seeds of the test plants are sown in normal soil and, after 24 hours, watered with the preparation of the active compound. It is expedient to keep constant the amount of water per unit area. The concentration of the active compound in the preparation is of no importance, only the amount of active compound applied per unit area being decisive. After three weeks, the degree of damage to the plants is rated in % damage in comparison to the development of the untreated control. The figures denote:

0%=no action (like untreated control)

100%=total destruction

In this test, the following results were obtained at an exemplary application rate of 125 g/ha, the active compounds being tolerated well to very well by sugar-beets:

    ______________________________________                                                                Compound of Preparation                                 Plant      % Activity  Example No.                                             ______________________________________                                         Digitaria  ≧80  Ia-3, Ib-5, Ib-6, Ic-4                                  Alopeccurus                                                                               ≧80  Ia-3, Ib-5, Ib-6, Ic-4                                  Lolium     ≧90  Ia-3, Ib-5, Ib-6, Ic-4                                  ______________________________________                                    

Example B

Post-emergence test

Solvent: 5 parts by weight of acetone

Emulsifier: 1 part by weight of alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration.

Test plants which have a height of 5-15 cm are sprayed with the preparation of the active compound in such a way as to apply the particular amounts of active compound desired per unit area.

After three weeks, the degree of damage to the plants is rated in % damage in comparison to the development of the untreated control. The figures denote:

0%=no action (like untreated control)

100%=total destruction

In this test the following results were obtained at an exemplary application rate of 125 g/ha, the active compounds being tolerated well to very well by soya beans:

    ______________________________________                                                               Compound of Preparation                                  Plant     % Activity  Example No.                                              ______________________________________                                         Cynodon   30          Ia-2, Ia-3, Ib-2, Ib-3,                                                        Ib-5, Ib-6, Ic-3, Ic-4                                   Echinochia                                                                               80          Ia-2, Ia-3, Ib-2, Ib-3,                                                        Ib-5, Ib-6, Ic-3, Ic-4                                   Sataria   80          Ia-2, Ia-3, Ib-2, Ib-3,                                                        Ib-5, Ib-6, Ic-3, Ic-4                                   ______________________________________                                    

Example C

Tetranychus test (OP-resistant)

Solvent: 3 parts by weight of dimethylformamide

Emulsifier: 1 part by weight of alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent and the stated amount of emulsifier, and the concentrate is diluted with water to the desired concentration.

Bean plants (Phaseolus vulgaris) which are heavily infested with all development stages of the greenhouse red spider mite or two-spotted spider mite (Tetranychus urticae) are treated by being dipped into the active compound preparation of the desired concentration.

After the desired time, the destruction is determined in %. 100% means that all spider mites have been destroyed; 0% means that no spider mites have been destroyed.

In this test, a destruction of 100% was shown after 7 days, for example, by the compound of the Preparation Example (Ic-3) at an exemplary active compound concentration of 0.02%.

Example: D

Blowfly larvae test

Test animals: Lucili cuprina larvae

Emulsifier: 35 parts by weight of ethylene glycol monomethyl ether 35 parts by weight of nonylphenol polyglycol ether

To produce a suitable preparation of active compound, three parts by weight of active compound are mixed with seven parts by weight of the abovementioned mixture and the resulting emulsion concentrate is diluted with water to the particular desired concentration.

About 20 Lucilia cuprina res. larvae are introduced into a test tube which contains approx. 1 cm³ of horse meat and 0.5 ml of the preparation of active compound. After 24 hours, the activity of the preparation of active compound is determined. 100% means that all blowfly larvae have been destroyed; 0% means that no blowfly larvae have been destroyed.

In this test, a destruction of 100% was shown, for example, by compound (Ia-3) of the Preparation Examples at an exemplary active compound concentration of 300 ppm. 

We claim:
 1. A 1-H-3[P]-phenyl-5-cycloalkylpyrrolidine-2,4-dione[s] of the formula [(I)] ##STR339## in which A represents optionally substituted cycloalkyl andB represents optionally substituted alkyl, X represents alkyl, halogen or alkoxy, Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl, Z represents alkyl, halogen or alkoxy, n represents a number 0, 1, 2 or 3, G represents hydrogen (a) or the groups ##STR340## L and M represent oxygen and/or sulphur, R¹ represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl, wherein said cycloalkyl group is optionally interrupted by hetero atoms, or represents optionally substituted phenyl, optionally substitute phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl,R² represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or in each case optionally substituted cycloalkyl, phenyl or benzyl, R⁴ and R⁵ independently of one another represent in each case optionally halogen-substituted alkyl, alkoxy, cycloalkyloxy, alkylamino, dialkylamino, alkylthio, alkenylthio or cycloalkylthio and in each case optionally substituted phenyl, phenoxy, benzyloxy or phenylthio, R⁶ and R⁷ independently of one another represent hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxy or alkoxyalkyl, optionally substituted phenyl, optionally substituted benzyl, or together with the N-atom to which they are bound represent a cycle which is optionally interrupted by oxygen or sulphur.
 2. A 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-dione according to claim 1, of the formula ##STR341## in which A, B, L, M, X, Y, Z_(n), R¹ and R² having the meanings given in claim
 1. 3. A 1-H-3-Phenyl-5-cycloalkylpyrrolidine-2,4-dione according to claim 1, in whichA represents C₃ -C₁₀ -cycloalkyl which is optionally substituted by halogen, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₁ -C₄ -halogenoalkyl or C₁ -C₄ -halogenoalkoxy, B represents hydrogen or optionally halogen-substituted straight-chain or branched alkyl, X represents C₁ -C₆ -alkyl, halogen or C₁ -C₆ -alkoxy, Y represents hydrogen, C₁ -C₆ -alkyl, halogen, C₁ -C₆ -alkoxy or C₁ -C₃ -halogenoalkyl, Z represents C₁ -C₆ -alkyl, halogen or C₁ -C₆ -alkoxy, G represents hydrogen (a) or the groups ##STR342## in which L and M in each case represent oxygen and/or sulphur, R¹ represents in each case optionally halogen-substituted C₁ -C₂₀ -alkyl, C₂ -C₂₀ -alkenyl, C₁ -C₈ -alkoxy-C₁ -C₈ -alkyl, C₁ -C₈ -alkylthio-C₁ -C₈ -alkyl, C₁ -C₈ -polyalkoxy-C₂ -C₈ -alkyl or cycloalkyl having 3 to 8 ring atoms, which is optionally interrupted by oxygen and/or sulphur atoms, or represents phenyl which is optionally substituted by halogen, nitro, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₁ -C₆ -halogenoalkyl, C₁ -C₆ -halogenoalkoxy, C₁ -C₆ -alkylthio or C₁ -C₆ -alkylsulphonyl, or represents phenyl-C₁ -C₆ -alkyl which is optionally substituted by halogen, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₁ -C₆ -halogenoalkyl or C₁ -C₆ -halogenoalkoxy, or represents hetaryl which is optionally substituted by halogen and/or C₁ -C₆ -alkyl, or represents phenoxy-C₁ -C₆ -alkyl which is optionally substituted by halogen and/or C₁ -C₆ -alkyl, or represents hetaryloxy-C₁ -C₆ -alkyl which is optionally substituted by halogen, amino and/or C₁ -C₆ -alkyl, R² represents in each case optionally halogen-substituted C₁ -C₂₀ -alkyl, C₃ -C₂₀ -alkenyl, C₁ -C₈ -alkoxy-C₂ -C₈ -alkyl or C₁ -C₈ -polyalkoxy-C₂ -C₈ -alkyl, or represents C₃ -C₈ -cycloalkyl which is optionally substituted by halogen, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy and/or C₁ -C₆ -alkylthio, or represents phenyl or benzyl, each of which is optionally substituted by halogen, nitro, C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy or C₁ -C₆ -halogenoalkyl-, R⁴ and R⁵ independently of one another represent in each case optionally halogen-substituted C₁ -C₈ -alkyl, C₁ -C₈ -alkoxy, C₃ -C₇ -cycloalkyloxy, C₁ -C₈ -alkylamino, di-(C₁ -C₈)-alkylamino, C₁ -C₈ -alkylthio, C₃ -C₈ -alkenylthio or C₃ -C₇ -cycloalkylthio, or represent phenyl, phenoxy or phenylthio, each of which is optionally substituted by halogen, nitro, cyano, C₁ -C₄ -alkoxy, C₁ -C₄ -halogenoalkoxy, C₁ -C₄ -alkylthio, C₁ -C₄ -halogenoalkylthio, C₁ -C₄ -alkyl or C₁ -C₄ -halogenoalkyl and R⁶ and R⁷ independently of one another represent hydrogen or represent in each case halogen-substituted C₁ -C₈ -alkyl, C₃ -C₈ -cycloalkyl, C₁ -C₈ -alkoxy, C₃ -C₈ -alkenyl or C₁ -C₈ -alkoxy-C₂ -C₈ -alkyl, or represent phenyl which is optionally substituted by halogen, C₁ -C₈ -halogenoalkyl, C₁ -C₈ -alkyl or C₁ -C₈ -alkoxy, or represent benzyl which is optionally substituted by halogen, C₁ -C₈ -alkyl, C₁ -C₈ -halogenoalkyl or C₁ -C₈ -alkoxy, or together with the nitrogen atom to which they are bound represent a ring having 3-6 C-atoms which is optionally interrupted by oxygen or sulphur.
 4. A 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-dione according to claim 1, in whichA represents C₃ -C₈ -cycloalkyl which is optionally substituted by fluorine, chlorine, C₁ -C₅ -alkyl, C₁ -C₅ -alkoxy, C₁ -C₂ -halogenoalkyl or C₁ -C₂ -halogenoalkoxy, B represents hydrogen or straight-chain or branched C₁ -C₆ -alkyl which is optionally substituted by chlorine or fluorine, X represents C₁ -C₄ -alkyl, halogen or C₁ -C₄ -alkoxy, Y represents hydrogen, C₁ -C₄ -alkyl, halogen, C₁ -C₄ -alkoxy or C₁ -C₂ -halogenoalkyl, Z represents C₁ -C₄ -alkyl, halogen or C₁ -C₄ -alkoxy; G represents hydrogen (a) or the groups ##STR343## in which L and M in each case represent oxygen and/or sulphur, R¹ represents in each case optionally halogen-substituted C₁ -C₁₆ -alkyl, C₂ -C₁₆ -alkenyl, C₁ -C₆ -alkoxy-C₁ -C₆ -alkyl, C₁ -C₁₆ -alkylthio-C₁ -C₆ -alkyl, C₁ -C₆ -polyalkoxy-C₂ -C₆ -alkyl or cycloalkyl having 3 to 7 ring atoms which can be interrupted by 1-2 oxygen and/or sulphur atoms, or represents phenyl which is optionally substituted by halogen, nitro, C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy, C₁ -C₃ -halogenoalkyl, C₁ -C₃ -halogenoalkoxy C₁ -C₆ -alkylthio or C₁ -C₆ -alkylsulphonyl, or represents phenyl-C₁ -C₄ -alkyl which is optionally substituted by halogen, C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy, C₁ -C₃ -halogenoalkyl or C₁ -C₃ -halogenoalkoxy, or represents hetaryl which is optionally substituted by fluorine, chlorine, bromine and/or C₁ -C₄ -alkyl, or represents phenoxy-C₁ -C₅ -alkyl which is optionally substituted by fluorine, chlorine, bromine, amino and/or C₁ -C₄ -alkyl, or represents hetaryloxy-C₁ -C₅ -alkyl which is optionally substituted by fluorine, chlorine, bromine, amino and/or C₁ -C₄ -alkyl, R² represents in each case optionally halogen-substituted C₁ -C₁₆ -alkyl, C₃ -C₁₆ -alkenyl, C₁ -C₆ -alkoxy-C₂ -C₆ -alkyl or C₁ -C₆ -polyalkoxy-C₂ -C₆ -alkyl, or represents C₃ --C₇ -cycloalkyl which is optionally substituted by halogen, C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy and/or C₁ -C₄ -alkylthio, or represents phenyl or benzyl, each of which is optionally substituted by halogen, nitro, C₁ -C₆ -alkyl, C₁ -C₃ -alkoxy or C₁ -C₃ -halogenoalkyl, R⁴ and R⁵ independently of one another represent in each case optionally halogen-substituted C₁ -C₆ -alkyl, C₁ -C₆ -alkoxy, C₃ -C₆ -cycloalkyloxy, C₁ -C₆ -alkylamino, di-(C₁ -C₆ -alkylamino, C₁ -C₆ -alkylthio, C₃ -C₆ -alkenylthio or C₃ -C₆ -cycloalkylthio, or represent phenyl, phenoxy, benzyloxy, or phenylthio, each of which is optionally substituted by fluorine, chlorine, bromine, nitro, cyano, C₁ -C₃ -alkoxy, C₁ -C₃ -halogenoalkoxy, C₁ -C₃ -alkylthio, C₁ -C₃ -halogenoalkylthio, C₁ -C₃ -alkyl or C₁ -C₃ -halogenoalkyl and R⁶ and R⁷ independently of one another represent hydrogen, or represent in each case optionally halogen-substituted C₁ -C₆ -alkyl, C₃ -C₆ -cycloalkyl, C₁ -C₆ -alkoxy, C₃ -C₆ -alkenyl or C₁ -C₆ -alkoxy-C₂ -C₆ -alkyl, or represent phenyl which is optionally substituted by halogen, C₁ -C₅ -halogenoalkyl, C₁ -C₅ -alkyl or C₁ -C₅ -alkoxy, or represent benzyl which is optionally substituted by halogen, C₁ -C₅ -alkyl, C₁ -C₅ -halogenoalkyl or C₁ -C₅ -alkoxy, or together with the N-atom to which they are bound represent a ring having 3-6 C-atoms which is optionally substituted by oxygen or sulphur.
 5. A 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-dione according to claim 1, in whichA represents C₃ -C₆ -cycloalkyl which is optionally substituted by fluorine, methyl, ethyl, propyl, i-propyl, butyl, i-butyl, s-butyl, methoxy, ethoxy, propoxy, i-propoxy, trifluoromethyl or trifluoromethoxy, t-butyl, B represents hydrogen or methyl, ethyl, propyl, i-propyl, butyl, i-butyl, s-butyl or t-butyl, each of which is optionally substituted by fluorine, X represents methyl, ethyl, propyl, i-propyl, fluorine, chlorine, bromine, methoxy or ethoxy, Y represents hydrogen, methyl, ethyl, propyl, i-propyl, butyl, i-butyl, tert.-butyl, fluorine, chlorine, bromine, methoxy, ethoxy or tri-fluoromethyl, Z represents methyl, ethyl, propyl, butyl, i-butyl, tert.-butyl, fluorine, chlorine, bromine, methoxy or ethoxy, i-propyl, G represents hydrogen (a) or the groups ##STR344## in which L and M represent oxygen and/or sulphur, R¹ represents in each case optionally fluorine- or chlorine-substituted C₁ -C₁₄ -alkyl, C₂ -C₁₄ -alkenyl, C₁ -C₄ -alkoxy-C₁ -C₆ -alkyl, C₁ -C₄ -alkylthio-C₁ -C₆ -alkyl, C₁ -C₄ -polyalkoxy-C₂ -C₄ -alkyl or cyaloalkyl having 3 to 6 ring atoms which can be interrupted by 1 to 2 oxygen and/or sulphur atoms, or represents phenyl which is optionally substituted by fluorine, chlorine, bromine, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy, trifluoromethyl, trifluoromethoxy, nitro, methylthio, ethylthio, methylsulphonyl or ethylsulphonyl, or represents phenyl-C₁ -C₃ -alkyl which is optionally substituted by fluorine, chlorine, bromine, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy, or represents furanoyl, thienyl, pyridyl, pyrimidyl, thiazolyl and pyrazolyl, each of which is optionally substituted by fluorine, chlorine, bromine, methyl or ethyl, or represents phenoxy-C₁ -C₄ -alkyl which is optionally substituted by fluorine, chlorine, methyl or ethyl, or represents pyridyloxy-C₁ -C₄ -alkyl, pyrimidyloxy-C₁ -C₄ -alkyl and thiazolyloxy-C₁ -C₄ -alkyl, each of which is optionally substituted by fluorine, chlorine, amino, methyl or ethyl, R² represents C₁ -C₁₄ -alkyl, C₃ -C₁₄ -alkenyl, C₁ -C₄ -alkoxy-C₂ -C₆ -alkyl or C₁ -C₄ -polyalkoxy-C₂ -C₆ -alkyl, each of which is optionally substituted by fluorine or chlorine, or represents C₃ -C₆ -cycloalkyl which is optionally substituted by fluorine, chlorine, methyl, ethyl, propyl, methoxy, ethoxy, methylthio or ethylthio, or represents phenyl or benzyl, each of which is optionally substituted by fluorine, chlorine, nitro, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy or trifluoromethyl, R⁴ and R⁵ independently of one another represent C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy, C₁ -C₄ -alkylamino, di-(C₁ -C₄)-alkylamino or C₁ -C₄ -alkylthio, each of which is optionally substituted by fluorine or chlorine, or represent phenyl, phenoxy, benzyloxy or phenylthio, each of which is optionally substituted by fluorine, chlorine, bromine, nitro, cyano, C₁ -C₂ -alkoxy, C₁ -C₄ -fluoroalkoxy, C₁ -C₂ -alkylthio, C₁ -C₂ -fluoroalkylthio or C₁ -C₃ -alkyl and R⁶ and R⁷ independently of one another represent hydrogen, or represent C₁ -C₄ -alkyl, C₃ -C₆ -cycloalkyl, C₁ -C₄ -alkoxy, C₃ -C₄ -alkenyl or C₁ -C₄ -alkoxy-C₂ -C₄ -alkyl, each of which is optionally substituted by fluorine, chlorine or bromine, or represent phenyl which is optionally substituted by fluorine, chlorine, bromine, C₁ -C₄ -halogenoalkyl, C₁ -C₄ -alkyl or C₁ -C₄ -alkoxy, or represent benzyl which is optionally substituted by fluorine, chlorine, bromine, C₁ -C₄ -alkyl, C₁ -C₄ -halogenoalkyl or C₁ -C₄ -alkoxy, or together with the N-atom to which they are bound represent a ring having 4-6 C-atoms which is optionally substituted by oxygen or sulphur.
 6. A pesticidal or herbicidal composition comprising an effective amount of a 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-dione according to claim 1 and an inert carrier.
 7. A method of combating pests, wherein a 1-H-3-phenyl-5-cycloalkylpyrrolidine-2,4-dione according to claim 1 is allowed to act on pests, undesired plants and/or their environment.
 8. A compound according to claim 1, which has the formula ##STR345## in which A represents C₃ -C₁₀ cycloalkyl,B represents C₁ -C₆ alkyl, X represents C₁ -C₄ alkyl or halogen; Y represents hydrogen, C₁ -C₄ alkyl or halogen, Z represents C₁ -C₄ alkyl or halogen, or R¹ represents C₁ -C₁₄ alkyl.
 9. A compound according to claim 1, which has the formula ##STR346## in which A represents C₃ -C₁₀ cycloalkyl,B represents C₁ -C₆ alkyl, X represents halogen, Y represents halogen, Z represents hydrogen.
 10. A compound according to claim 1, which has the formula ##STR347## in which A represents C₃ -C₁₀ cycloalkyl,B represents C₁ -C₆ alkyl, X represents halogen, Y represents halogen, Z represents hydrogen, and C₁ -C₄ alkyl and R² represents C₁ -C₁₄ alkyl.
 11. A compound according to claim 1, which has the formula ##STR348## in which A represents C₃ -C₁₀ cycloalkyl,B represents C₁ -C₆ alkyl, L represents S or O, X represents C₁ -C₄ alkyl, Y represents C₁ -C₄ alkyl, Z represents hydrogen, R⁴ represents C₁ -C₄ alkyl, and R⁵ represents C₁ -C₄ alkoxy or C₁ -C₄ alkylthio.
 12. A compound according to claim 1, wherein R¹ and R² represent C₁ -C₁₄ alkyl, C₃ -C₇ cycloalkyl, phenyl or benzyl.
 13. A compound according to claim 10, wherein L is oxygen.
 14. A compound according to claim 10, which has the following formula ##STR349##
 15. A compound according to claim 9, which as the formula ##STR350##
 16. A compound according to claim 8, which has the formula ##STR351##
 17. A compound according to claim 11, which has the formula ##STR352##
 18. A compound according to claim 10, which has the formula ##STR353##
 19. A compound according to claim 1, which has the formula ##STR354## in which A represents C₃ -C₁₀ cycloallyl,B represents C₁ -C₆ allyl, X represents H or C₁ -C₄ alkyl, Y represents H or C₁ -C₄ allyl, R⁶ and R⁷ independently of one another represent hydrogen, or represent in each case optionally halogen-substituted C₁ -C₆ -alkyl, C₃ -C₆ -cycloalkyl, C₁ -C₆ -alkoxy, C₃ -C₆ -alkenyl or C₁ -C₆ -alkoxy-C₂ -C₆ -alkyl, or represent phenyl which is optionally substituted by halogen, C₁ -C₅ -halogenoalkyl, C₁ -C₅ -alkyl or C₁ -C₅ -alkoxy, or represent benzyl which is optionally substituted by halogen, C₁ -C₅ -alkyl, C₁ -C₅ -halogenoalkyl or C₁ -C₅ -alkoxy, or together represent morpholine.
 20. A compound according to claim 19, which has the formula ##STR355## 